Chiral phosphoric acids (CPAs) have been used as efficient organocatalysts since the first
examples were reported 18 years ago by Akiyama and Terada. Although they were …

Chiral Phosphoric Acids (CPAs) are a highly versatile class of Brønsted acid organocatalysts
that have witnessed a surge in their use in asymmetric synthesis in recent years. Various …

Catalytic enantioselective introduction of a propargyl group constitutes one of the most
important carbon–carbon forming reactions, as it is versatile to be transformed into diverse …

Cu-catalyzed highly stereoselective and enantiodivergent syntheses of (Z)-or (E)-β, γ-
unsaturated ketones from 1, 3-butadienyl silanes are developed. The nature of the silyl …

We report herein a Cu‐catalyzed regio‐, diastereo‐and enantioselective acylboration of 1, 3‐
butadienylboronate with acyl fluorides. Under the developed conditions, the reactions …

The development of α, α-disubstituted crotylboronate reagents is reported. Chiral Brønsted
acid-catalyzed asymmetric aldehyde addition with the developed E-crotylboron reagent …

We report herein the development of stereodivergent syntheses of enantioenriched
homoallylic alcohols using chiral nonracemic α‐CH2Bpin‐substituted crotylboronate. Chiral …

We report herein a rare example of enantiodivergent aldehyde addition with β‐alkenyl allylic
boronates via chiral Brønsted acid catalysis. 2, 6‐Di‐9‐anthracenyl‐substituted chiral …

We report a dual function asymmetric catalysis by a chiral phosphoric acid catalyst that
controls both enantioselective addition of an achiral α‐vinyl allylboronate to aldehydes and …

Stereoselective synthesis of (Z)-α-boryl-crotylboronate is developed. Ni-catalyzed Z-
selective alkene isomerization of α-boryl substituted homoallylboronate provided the …