Azines, such as pyridines, quinolines, pyrimidines, and pyridazines, are widespread
components of pharmaceuticals. Their occurrence derives from a suite of physiochemical …

Transition-metal-catalyzed C–H activation has developed a contemporary approach to the
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …

Alkoxy radicals are highly reactive species that have long been recognized as versatile
intermediates in organic synthesis. However, their development has long been impeded due …

For more than 70 years, nitrogen-centered radicals have been recognized as potent
synthetic intermediates. This review is a survey designed for use by chemists engaged in …

The fields of C–H functionalization and photoredox catalysis have garnered enormous
interest and utility in the past several decades. Many different scientific disciplines have …

The generation of heteroatom-centred radicals (X˙), followed by intramolecular 1, 5-
hydrogen atom transfer (1, 5-HAT) and the functionalisation of the translocated carbon …

The late stage functionalization (LSF) of complex biorelevant compounds is a powerful tool
to speed up the identification of structure–activity relationships (SARs) and to optimize …

Conspectus The radical-mediated C–H functionalization of pyridines has attracted
considerable attention as a powerful tool in synthetic chemistry for the direct …

The selective installation of azide groups into C (sp3)–H bonds is a priority research topic in
organic synthesis, particularly in pharmaceutical discovery and late-stage diversification …

Pyridinium salts are valuable building blocks, which have been widely applied in various
organic transformations during the past few decades. In particular, N-functionalized …