The tetracationic cyclophane, cyclobis (paraquat‐p‐phenylene), also known as the little blue
box, constitutes a modular receptor that has facilitated the discovery of many host–guest …

Radical-pairing interactions between conjugated organic π-radicals are relative newcomers
to the inventory of molecular recognition motifs explored in supramolecular chemistry. The …

During the past few decades, fabrication of functional rotaxane-branched dendrimers has
become one of the most attractive yet challenging topics within supramolecular chemistry …

Daisy chain architectures, made by the self-complementary threading of an axle covalently
linked to a macrocycle, represent a particularly intriguing family of supramolecular and …

Molecular photoelectrochemical devices are hampered by electron–hole recombination
after photoinduced electron transfer, causing losses in power conversion efficiency. Inspired …

Supramolecular polymers are, in broad brushstrokes, self-assembled structures built up from
small building blocks via the use of noncovalent interactions. In favorable cases …

Although a large number of novel supramolecular topologies featuring half-sandwich [Cp*
Rh] units have been reported, investigations into the properties of these architectures are …

Reflecting on recent progress in bottom-up engineering focused on creating the smallest
devices capable of controlling nanoscale motion, artificial molecular pumps (AMPs) are …

Artificial molecular pumps (AMPs), inspired by the active cellular transport exhibited in
biological systems, enable cargoes to undergo unidirectional motion, courtesy of molecular …

Mechanically interlocked polymers (MIPs) are capable of synchronously directing force and
motion empowered by collective mechanical bonds, thus constituting a versatile platform for …