In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …

The synthesis of sulfones via a selective functionalization of C–H-bonds represents a
powerful alternative to classical methods for the preparation of this important compound …

Synthesis of biaryls via the Suzuki–Miyaura coupling (SMC) reaction using nitroarenes as
an electrophilic coupling partners is described. Mechanistic studies have revealed that the …

Functionalization of arenes is a topic of central importance in diverse fields ranging from
medicinal chemistry to materials science. Metal-catalyzed cross-coupling and nucleophilic …

The activation of σ-bonds by transition metals underpins a wide range of methods for the
synthesis of complex molecules. Within this context, C–N bond activation has emerged …

The cleavage of an unactivated aryl nitro group triggered by alkyl radicals enables a
dearomative cyclization, affording diversified alkylated spiro [5.5] trienones in good yields …

A new approach to C− S couplings is reported that relies on nickel catalysis under mild
conditions, enabled by micellar catalysis in recyclable water as the reaction medium. The …

Palladium-catalyzed denitrative Suzuki coupling of nitroarenes using 2-aryl-5-(2, 4, 6-
triisopropylphenyl)-2, 3-imidazolylidene [1, 5-a] pyridines as the ligands is described. The …

Convenient MW-Assisted Synthesis of Unsymmetrical Sulfides Using Sulfonyl Hydrazides as
Aryl Thiol Surrogate | Organic Letters ACS ACS Publications C&EN CAS Find my institution Log …

In this article, we report three odorless methods for the thioarylation and thioalkylation of
different nitroarenes using alkyl halides (Br, Cl), triphenyltin chloride, and arylboronic acids …