From an antiferromagnetic insulator to a strongly correlated metal in square-lattice MCl2(pyrazine)2 coordination solids
Electronic synergy between metal ions and organic linkers is a key to engineering molecule-
based materials with a high electrical conductivity and, ultimately, metallicity. To enhance …
based materials with a high electrical conductivity and, ultimately, metallicity. To enhance …
Substantiation to structure-property of pyrazine-based compounds by undeniable impress of its different connectivities
In this review, we explain how pyrazine (hereafter as pz) leds to various structures spanning
from multicomponent molecular crystals to coordination polymers. An important factor in the …
from multicomponent molecular crystals to coordination polymers. An important factor in the …
Strong coupling of microwave photons to antiferromagnetic fluctuations in an organic magnet
Coupling between a crystal of di (phenyl)-(2, 4, 6-trinitrophenyl) iminoazanium radicals and
a superconducting microwave resonator is investigated in a circuit quantum electrodynamics …
a superconducting microwave resonator is investigated in a circuit quantum electrodynamics …
Self-Assembled Tetranuclear Square Complex of Chromium (III) Bridged by Radical Pyrazine: A Molecular Model for Metal–Organic Magnets
D Lou, NJ Yutronkie, I Oyarzabal… - Journal of the …, 2024 - ACS Publications
The attractive electronic properties of metal-pyrazine materials─ electrical conductivity,
magnetic order, and strong magnetic coupling─ can be tuned in a wide range depending …
magnetic order, and strong magnetic coupling─ can be tuned in a wide range depending …
Synthesis, crystal structure, and magnetic properties of a new one-dimensional chain antiferromagnet Co(ox)(bib)·H2O (ox = oxalate; bib = 1,4-bis(imidazole-1-yl) …
Y She, Y Wang, S Li, T Wang, H Lu - Nano Research, 2023 - Springer
A new one-dimensional (1D) chain antiferromagnet Co (ox)(bib)· H2O 1 (ox= oxalate; bib= 1,
4-bis (imidazole-1-yl) benzene) has been successfully synthesized under hydrothermal …
4-bis (imidazole-1-yl) benzene) has been successfully synthesized under hydrothermal …
Low-dimensional quantum magnetism in : A molecular framework material
Low-dimensional magnetic materials with spin-1 2 moments can host a range of exotic
magnetic phenomena due to the intrinsic importance of quantum fluctuations to their …
magnetic phenomena due to the intrinsic importance of quantum fluctuations to their …
Enhancing easy-plane anisotropy in bespoke Ni (II) quantum magnets
JL Manson, ZE Manson, A Sargent, DY Villa, NL Etten… - Polyhedron, 2020 - Elsevier
We examine the crystal structures and magnetic properties of several S= 1 Ni (II)
coordination compounds, molecules and polymers, that include the bridging ligands HF 2 …
coordination compounds, molecules and polymers, that include the bridging ligands HF 2 …
Combining microscopic and macroscopic probes to untangle the single-ion anisotropy and exchange energies in an quantum antiferromagnet
The magnetic ground state of the quasi-one-dimensional spin-1 antiferromagnetic chain is
sensitive to the relative sizes of the single-ion anisotropy (D) and the intrachain (J) and …
sensitive to the relative sizes of the single-ion anisotropy (D) and the intrachain (J) and …
Spatially anisotropic square-lattice antiferromagnet with single-ion anisotropy realized in a Ni(II) pyrazine--dioxide coordination polymer
JL Manson, DM Pajerowski, JM Donovan, B Twamley… - Physical Review B, 2023 - APS
The Ni (NCS) 2 (pyzdo) 2 coordination polymer is found to be an S= 1 spatially anisotropic
square lattice with easy-axis single-ion anisotropy. This conclusion is based upon …
square lattice with easy-axis single-ion anisotropy. This conclusion is based upon …
Magnetic ground state of the one-dimensional ferromagnetic chain compounds ()
SPM Curley, R Scatena, RC Williams, PA Goddard… - Physical Review …, 2021 - APS
The magnetic properties of the two isostructural molecule-based magnets—Ni (NCS) 2
(thiourea) 2, S= 1 [thiourea= SC (NH 2) 2] and Co (NCS) 2 (thiourea) 2, S= 3/2—are …
(thiourea) 2, S= 1 [thiourea= SC (NH 2) 2] and Co (NCS) 2 (thiourea) 2, S= 3/2—are …