Assembly of Biaryl Amines via Mild Copper-Catalyzed Coupling of Anilines with (Hetero) aryl Chlorides/Bromides

S Li, L Xu, B An, D Ma - Organic Letters, 2025 - ACS Publications
CuI/6-hydroxy picolinohydrazide-catalyzed coupling of (hetero) aryl chlorides with anilines
proceeded well at 100° C to afford biaryl amines in a diverse manner, which represents the …

Enabling Room-Temperature Copper Cross-Coupling Reactions of Anilines with Aryl Bromides

J Hillenbrand, B König, J Düker, N Petersen, N Richter… - 2024 - chemrxiv.org
Biaryl amines are essential structural motifs prevalent in agrochemicals, pharmaceuticals,
and materials. Herein, we present a novel copper-catalyzed method for aniline cross …

Decoding Regioselectivity in Cu (I)-Catalyzed Borylation of Al-kynes: Insights from Machine Learning and Artificial Intelligence

G Marcos-Ayuso, D Quesada, SF Moyano, CL Sanchez… - 2025 - chemrxiv.org
Vinyl boronates are highly valuable intermediates in chemical synthesis, extensively used in
C‒C bond-forming reactions such as catalytic cross-coupling. Transition metal-catalyzed …