Polyoxometalates (POMs): from electroactive clusters to energy materials

MR Horn, A Singh, S Alomari… - Energy & …, 2021 - pubs.rsc.org
Polyoxometalates (POMs) represent a class of nanomaterials, which hold enormous
promise for a range of energy-related applications. Their promise is owing to their “special” …

Polyoxometalate‐based compounds for photo‐and electrocatalytic applications

N Li, J Liu, BX Dong, YQ Lan - … Chemie International Edition, 2020 - Wiley Online Library
Photo/electrocatalysis of water (H2O) splitting and CO2 reduction reactions is a promising
strategy to alleviate the energy crisis and excessive CO2 emissions. For the hydrogen …

Design of molecular water oxidation catalysts with earth-abundant metal ions

M Kondo, H Tatewaki, S Masaoka - Chemical Society Reviews, 2021 - pubs.rsc.org
The four-electron oxidation of water (2H2O→ O2+ 4H++ 4e−) is considered the main
bottleneck in artificial photosynthesis. In nature, this reaction is catalysed by a Mn4CaO5 …

Controlled synthesis of Ni (OH) 2/Ni 3 S 2 hybrid nanosheet arrays as highly active and stable electrocatalysts for water splitting

X Du, Z Yang, Y Li, Y Gong, M Zhao - Journal of Materials Chemistry A, 2018 - pubs.rsc.org
The efficiency and stability of electrocatalysts are the key factors influencing the process of
overall water splitting. In the research reported in this paper, the universal two-step method …

Recent advances of mixed-transition-metal-substituted polyoxometalates

Z Wang, X Xin, M Zhang, Z Li, H Lv, GY Yang - Science China Chemistry, 2022 - Springer
Polyoxometalates (POMs) have been emerging as one of the most widely-studied
interdisciplinary research fields of inorganic chemistry due to their structural diversities and …

[PDF][PDF] Recent advances in catalysts based on molecular cubanes for visible light-driven water oxidation

W Sun, J Lin, X Liang, J Yang, B Ma… - Acta Phys.-Chim. Sin …, 2020 - whxb.pku.edu.cn
Increasing climate change and environmental pollution caused by the excessive use of
fossil fuels have prompted intensive research into clean and efficient renewable sources as …

In situ grown pristine cobalt sulfide as bifunctional photocatalyst for hydrogen and oxygen evolution

M Zheng, Y Ding, L Yu, X Du… - Advanced Functional …, 2017 - Wiley Online Library
Herein, transition metal chalcogenides of pristine cobalt sulfides are rationally designed to
act as robust bifunctional photocatalysts for visible‐light‐driven water splitting for the first …

Recent advances in lanthanide-coordinated polyoxometalates: from structural overview to functional materials

CM Granadeiro, D Julião, SO Ribeiro… - Coordination Chemistry …, 2023 - Elsevier
Lanthanopolyoxometalates (LnPOMs), obtained through the coordination of
polyoxometalates (POMs) and lanthanide ions (Ln), have received extraordinary interest of …

Interaction of Single-Atom Platinum–Oxygen Vacancy Defects for the Boosted Photosplitting Water H2 Evolution and CO2 Photoreduction: Experimental and …

S Cai, L Wang, S Heng, H Li, Y Bai… - The Journal of …, 2020 - ACS Publications
The incorporation of oxygen vacancy defects into the catalysts has been attracting significant
interest for regulating the performance of photocatalysts. Single-atomic-site metal catalysts …

Hepta-Zr-incorporated polyoxometalate assembly

PY Zhang, Y Wang, LY Yao, GY Yang - Inorganic Chemistry, 2022 - ACS Publications
Driven by the synergistic-directing effect of the lacunary fragments,[B-α-GeW9O34] 10–and
[B-α-GeW11O39] 8–, an unprecedented hepta-Zr-substituted polyoxometalate (POM) …