Progress and prospects in copper-catalyzed C–H functionalization

T Aneeja, M Neetha, CMA Afsina, G Anilkumar - RSC advances, 2020 - pubs.rsc.org
Copper-catalyzed C–H functionalization is becoming a significant area in organic chemistry.
Copper is now widely used as a catalyst in organic synthesis as it is inexpensive and not …

C3‐Functionalized Chromones Synthesis by Tandem C− H Elaboration and Chromone Annulation of Enaminones

L Fu, JP Wan - Asian Journal of Organic Chemistry, 2019 - Wiley Online Library
Chromone is a heterocyclic entity presents in a number of natural products, clinical
pharmaceuticals, as well as molecules with enriched biological functions. As cutting‐edge …

Copper-catalyzed asymmetric C(sp2)–H arylation for the synthesis of P- and axially chiral phosphorus compounds

SB Yan, R Wang, ZG Li, AN Li, C Wang… - Nature …, 2023 - nature.com
Transition metal-catalyzed C–H bond functionalization is an important method in organic
synthesis, but the development of methods that are lower cost and have a less …

Recent advances and perspectives in manganese-catalyzed C–H activation

T Aneeja, M Neetha, CMA Afsina… - Catalysis Science & …, 2021 - pubs.rsc.org
Manganese-catalyzed C–H activation has emerged as a powerful tool in organic synthesis
within a few years. These reactions are highly selective, eco-friendly and exhibit a wide …

Recent Advances in Copper Promoted Inert C(sp3)–H Functionalization

Y Yang, W Gao, Y Wang, X Wang, F Cao, T Shi… - ACS …, 2021 - ACS Publications
Copper-promoted inert C (sp3)–H functionalization has gradually been developed as a
nascent tool to establish categories of bonds, including C (sp3)–C, C (sp3)–N, C (sp3)–O/S …

Amine‐Catalyzed Copper‐Mediated C− H Sulfonylation of Benzaldehydes via a Transient Imine Directing Group

JI Higham, JA Bull - Angewandte Chemie International Edition, 2022 - Wiley Online Library
Transient directing groups (TDGs) can provide a powerful means for C− H functionalization
without requiring additional steps for directing group introduction and removal. We report the …

Traceless directing groups in sustainable metal-catalyzed C–H activation

A Zarkadoulas, I Zgouleta, NV Tzouras… - Catalysts, 2021 - mdpi.com
Sustainable transformations towards the production of valuable chemicals constantly attract
interest, both in terms of academic and applied research. C–H activation has long been …

Redox-neutral C–H annulation strategies for the synthesis of heterocycles via high-valent Cp* Co (iii) catalysis

N Bhaduri, AB Pawar - Organic & Biomolecular Chemistry, 2023 - pubs.rsc.org
A variety of biologically active molecules, pharmaceuticals, and natural products consist of a
nitrogen-containing heterocyclic backbone. The majority of them are isoquinolones, indoles …

[HTML][HTML] On the application of 3d metals for C–H activation toward bioactive compounds: The key step for the synthesis of silver bullets

RL Carvalho, AS de Miranda… - Beilstein Journal of …, 2021 - beilstein-journals.org
Several valuable biologically active molecules can be obtained through C–H activation
processes. However, the use of expensive and not readily accessible catalysts complicates …

Copper‐Mediated and Catalyzed C—H Bond Amination via Chelation Assistance: Scope, Mechanism and Synthetic Applications

JL Ma, XM Zhou, PH Guo… - Chinese Journal of …, 2022 - Wiley Online Library
Comprehensive Summary Nitrogen‐containing compounds are ubiquitously found in the
fields of organic chemistry, pharmaceuticals, agrochemicals, medicinal chemistry and …