Synthesis of Biaryls through Aromatic C H Bond Activation: A Review of Recent Developments

I Hussain, T Singh - Advanced Synthesis & Catalysis, 2014 - Wiley Online Library
This review describes recent progress made in the rapidly developing field of C H bond
activation, in particular for syntheses of biaryls. The catalysts presented here provide …

Recent Advances in Organocatalytic Methods for Asymmetric C C Bond Formation

U Scheffler, R Mahrwald - Chemistry–A European Journal, 2013 - Wiley Online Library
Beyond a doubt organocatalysis belongs to the most exciting and innovative chapters of
organic chemistry today. Organocatalysis has emerged not only as a complement to metal …

KOtBu: A Privileged Reagent for Electron Transfer Reactions?

JP Barham, G Coulthard, KJ Emery… - Journal of the …, 2016 - ACS Publications
Many recent studies have used KO t Bu in organic reactions that involve single electron
transfer; in the literature, the electron transfer is proposed to occur either directly from the …

Electrochemical synthesis of biaryls by reductive extrusion from N,N'-diarylureas

E Stammers, CD Parsons, J Clayden… - Nature …, 2023 - nature.com
The synthesis of biaryl compounds by the transition-metal free coupling of arenes is an
important contemporary challenge, aiming to avoid the toxicity and cost profiles associated …

Simple and efficient generation of aryl radicals from aryl triflates: synthesis of aryl boronates and aryl iodides at room temperature

W Liu, X Yang, Y Gao, CJ Li - Journal of the American Chemical …, 2017 - ACS Publications
Despite the wide use of aryl radicals in organic synthesis, current methods to prepare them
from aryl halides, carboxylic acids, boronic acids, and diazonium salts suffer from limitations …

A chemical-enhanced system for CRISPR-Based nucleic acid detection

Z Li, W Zhao, S Ma, Z Li, Y Yao, T Fei - Biosensors and Bioelectronics, 2021 - Elsevier
The CRISPR-based nucleic acid detection systems have shown great potential for point-of-
care testing of viral pathogens, especially in the context of COVID-19 pandemic. Here we …

l-Proline: An Efficient Catalyst for Transamidation of Carboxamides with Amines

SN Rao, DC Mohan, S Adimurthy - Organic letters, 2013 - ACS Publications
l-Proline: An Efficient Catalyst for Transamidation of Carboxamides with Amines | Organic Letters
ACS ACS Publications C&EN CAS Find my institution Log In Organic Letters ACS Publications …

Organic super-electron-donors: initiators in transition metal-free haloarene–arene coupling

S Zhou, GM Anderson, B Mondal, E Doni… - Chemical …, 2014 - pubs.rsc.org
Recent papers report transition metal-free couplings of haloarenes to arenes to form biaryls,
triggered by alkali metal tert-butoxides in the presence of various additives. These reactions …

Recent advances in transition-metal-free direct C–C and C–heteroatom bond forming reactions

VP Mehta, B Punji - RSC advances, 2013 - pubs.rsc.org
The efficient generation of biaryl compounds and heterocycles via the advent of the
transition-metal-free coupling reaction constitutes an important development in the last few …

Identifying the roles of amino acids, alcohols and 1, 2-diamines as mediators in coupling of haloarenes to arenes

S Zhou, E Doni, GM Anderson, RG Kane… - Journal of the …, 2014 - ACS Publications
Coupling of haloarenes to arenes has been facilitated by a diverse range of organic
additives in the presence of KO t Bu or NaO t Bu since the first report in 2008. Very recently …