Comb and bottlebrush polymers with superior rheological and mechanical properties

M Abbasi, L Faust, M Wilhelm - Advanced Materials, 2019 - Wiley Online Library
Comb and bottlebrush polymers present a wide range of rheological and mechanical
properties that can be controlled through their molecular characteristics, such as the …

Perspectives on the viscoelasticity and flow behavior of entangled linear and branched polymers

F Snijkers, R Pasquino, PD Olmsted… - Journal of Physics …, 2015 - iopscience.iop.org
We briefly review the recent advances in the rheology of entangled polymers and identify
emerging research trends and outstanding challenges, especially with respect to branched …

Materials design of highly branched bottlebrush polymers at the intersection of modeling, synthesis, processing, and characterization

T Pan, S Dutta, Y Kamble, BB Patel… - Chemistry of …, 2022 - ACS Publications
Highly branched “bottlebrush” polymers are a class of macromolecules characterized by
side chains that are densely grafted from a backbone that is typically linear. Their unique …

Design, synthesis, and self-assembly of polymers with tailored graft distributions

AB Chang, TP Lin, NB Thompson… - Journal of the …, 2017 - ACS Publications
Grafting density and graft distribution impact the chain dimensions and physical properties of
polymers. However, achieving precise control over these structural parameters presents …

Effects of grafting density on block polymer self-assembly: From linear to bottlebrush

TP Lin, AB Chang, SXL Luo, HY Chen, B Lee… - ACS …, 2017 - ACS Publications
Grafting density is an important structural parameter that exerts significant influences over
the physical properties of architecturally complex polymers. In this report, the physical …

Linear and extensional rheology of model branched polystyrenes: From loosely grafted combs to bottlebrushes

M Abbasi, L Faust, K Riazi, M Wilhelm - Macromolecules, 2017 - ACS Publications
Monodisperse comb polystyrenes (comb-PS) with loosely to densely grafted architectures
up to loosely grafted bottlebrush structures were synthesized via anionic polymerization …

Synthesis and linear and nonlinear melt rheology of well-defined comb architectures of PS and PpMS with a low and controlled degree of long-chain branching

M Kempf, D Ahirwal, M Cziep, M Wilhelm - Macromolecules, 2013 - ACS Publications
Well-defined, monodisperse homopolymer comb architectures with varied number and
length of the branches under linear and nonlinear deformation were synthesized and …

Homogeneous shear, wall slip, and shear banding of entangled polymeric liquids in simple-shear rheometry: A roadmap of nonlinear rheology

SQ Wang, S Ravindranath, PE Boukany - Macromolecules, 2011 - ACS Publications
The recent particle-tracking velocimetric (PTV) observations revealed that well-entangled
polymer solutions and melts tend to either exhibit wall slip or assume an inhomogeneous …

Linear and nonlinear shear rheology of a marginally entangled ring polymer

ZC Yan, S Costanzo, Y Jeong, T Chang… - …, 2016 - ACS Publications
We present systematic, unique linear and nonlinear shear rheology data of an
experimentally pure ring polystyrene and its linear precursor. This polymer was synthesized …

Nanostructures, Linear Rheological Responses, and Tunable Mechanical Properties of Microphase-Separated Cellulose-graft-Diblock Bottlebrush Copolymer …

H Sun, X Wang, Q Chen, Z Wang - Biomacromolecules, 2023 - ACS Publications
A series of cellulose-graft-diblock bottlebrush copolymer elastomers (cellulose-graft-poly (n-
butyl acrylate)-block-poly (methyl methacrylate)(Cell-g-PBA-b-PMMA)) with short side chains …