The utilization of visible light to mediate chemical reactions in fluid solutions has
applications that range from solar fuel production to medicine and organic synthesis. These …

Although photoredox catalysis is complex from a mechanistic point of view, it is also often
surprisingly efficient. In fact, the quantum efficiency of a puzzlingly large portion of …

Photoredox catalysis is a powerful tool to access challenging and diverse syntheses.
Absorption of visible light forms the excited state catalyst (* PC) but photons may be wasted …

Photocatalysis that uses the energy of light to promote chemical transformations by
exploiting the reactivity of excited-state molecules is at the heart of a virtuous dynamic within …

Photocatalysis holds great promise for changing the way value-added molecules are
currently prepared. However, many photocatalytic reactions suffer from quantum yields well …

The cage escape yield, ie, the separation of the geminate radical pair formed immediately
after bimolecular excited-state electron transfer, was studied in 11 solvents using six Fe (III) …

Inefficient photo-carrier separation and sluggish photoreaction dynamics appreciably
undermine the photocatalytic decontamination efficacy of photocatalysts. Herein, an S …

Excited-state quenching and reduction of [Fe (phtmeimb) 2]+, where phtmeimb is phenyl [tris
(3-methyl-imidazolin-2-ylidene)] borate, with iodide, bromide, and chloride were studied in …

Reverse intersystem crossing (RISC) has become possible by minimizing the energy gap
between the first excited singlet (S1) and triplet state (T1), which facilitates the thermally …

Six-coordinate chromium (III) complexes with high spin-flip (SF) photoluminescence
quantum yields and lifetimes (molecular rubies) have attracted huge interest in the past …