Photoactivatable (alternatively, photoremovable, photoreleasable, or photocleavable)
protecting groups (PPGs), also known as caged or photocaged compounds, are used to …

Although iron is among the most abundant of the bio-essential transition metals and its
coordination chemistry is of central importance to bio-inorganic and bioinspired chemistry …

The potential of carbon monoxide to act as a therapeutic agent is now well-established.
Controlled delivery of CO is best achieved using 'CORMs': molecules which release known …

Several beneficial biological effects of carbon monoxide (CO) have been identified. CO
contributes to vascular tone, is anti-inflammatory and antiapoptotic, and protects tissue …

Abstract When Ziegler and Korav serendipitously prepared [Fe 2 (CO) 6 (μ-pdt)] in 1979 they
could not have anticipated that some 40 years later it would be a mainstay of attempts to …

Iron carbonyl complexes are a large category of classic transition metal complexes. In
addition to their vast range of applications in catalysis, they have been found to be of …

Iron–thiolate complexes of the type [Fe2 (μ‐bdt)(CO) 6− xP (OMe3) x](bdt= S2C6H4=
benzenedithiolate, x≤ 2) are simplified models of iron–iron hydrogenase enzymes …

The diiron hydride [(μ-H) Fe2 (pdt)(CO) 4 (dppv)]+([H 2]+, dppv= cis-1, 2-C2H2 (PPh2) 2) is
shown to be an effective photocatalyst for the H2 evolution reaction (HER). These …

This perspective aims at illustrating a computational viewpoint on some specific issues
concerning structure–activity relationships related to [FeFe]-hydrogenase ([FeFe]-H2ase) …

Hydrogenases are enzymes that catalyze the oxidation and production of molecular
hydrogen. For about fifteen years, there have been many reports about the successful …