The bridging azido ligand as a central “player” in high-nuclearity 3d-metal cluster chemistry

A Escuer, J Esteban, SP Perlepes… - Coordination Chemistry …, 2014 - Elsevier
The chemistry of the azido-bridged coordination clusters continues to attract the intense
interest of synthetic inorganic chemists and scientists working in the interdisciplinary field of …

Azide as a bridging ligand and magnetic coupler in transition metal clusters

A Escuer, G Aromí - European journal of inorganic chemistry, 2006 - Wiley Online Library
The synthesis of transition metal spin‐clusters has become an important sub‐discipline of
coordination chemistry, especially since the discovery of single‐molecule magnets (SMMs) …

Azide chemistry–an inorganic perspective, Part I metal azides: overview, general trends and recent developments

WP Fehlhammer, W Beck - Zeitschrift für anorganische und …, 2013 - Wiley Online Library
Abstract With Sharpless' and Meldal's discovery of the immensely supportive effect that
metal catalysis has on Huisgen's classical 1, 3‐dipolar cycloaddition, azides (RN3)–long …

Structural Variety and Magnetic Properties of Tetranuclear Nickel(II) Complexes with a Central μ4-Azide

S Demeshko, G Leibeling, W Maringgele… - Inorganic …, 2005 - ACS Publications
Using a set of pyrazolate-based dinucleating ligands with thioether sidearms and a set of
different carboxylates, seven tetranuclear nickel (II) complexes of types [L2Ni4 (N3) 3 …

Strong ferromagnetic exchange coupling in a {Ni II4} cluster mediated through an air-stable tetrazine-based radical anion

MA Lemes, G Brunet, A Pialat, L Ungur… - Chemical …, 2017 - pubs.rsc.org
A planar tetradentate 3, 6-bis (2-pyrimidyl)-1, 2, 4, 5-tetrazine (BpymTz) templating chelate
affords the formation of an unprecedented BpymTz˙− radical anion bridged {NiII4} complex …

Structures and Magnetic Properties of Tetranuclear Nickel(II) Complexes with Unusual μ3‐1,1,3 Azido Bridges

F Meyer, S Demeshko, G Leibeling… - … A European Journal, 2005 - Wiley Online Library
Pyrazolate‐based dinucleating ligands with thioether‐containing chelate arms have been
used for the synthesis of a family of novel tetranuclear nickel (ii) complexes [L2Ni4 (N3) 3 …

Assembly of Azido- or Cyano-Bridged Binuclear Complexes Containing the Bulky [Mn(phen)2]2+ Building Block:  Syntheses, Crystal Structures, and Magnetic …

ZH Ni, HZ Kou, L Zheng, YH Zhao, LF Zhang… - Inorganic …, 2005 - ACS Publications
Two new cyano-bridged heterobinuclear complexes,[MnII (phen) 2Cl][FeIII (bpb)(CN) 2]⊙
0.5 CH3CH2OH⊙ 1.5 H2O (1) and [MnII (phen) 2Cl][CrIII (bpb)(CN) 2]⊙ 2H2O (2)[phen= 1 …

Coordination chemistry of Robson-type polyamine-dithiophenolate macrocycles: Syntheses, structures and magnetic properties of dinuclear complexes of first-row …

V Lozan, C Loose, J Kortus, B Kersting - Coordination Chemistry Reviews, 2009 - Elsevier
The coordination chemistry of N-functionalized derivatives of Robson-type macrocyclic
hexamine-dithiophenolate ligands (LR) 2− is presented in this review. The ligands form …

Syntheses, structures, and magnetic properties of three one-dimensional end-to-end azide/cyanate-bridged copper (II) compounds exhibiting ferromagnetic interaction …

S Sasmal, S Sarkar, N Aliaga-Alcalde… - Inorganic …, 2011 - ACS Publications
The work in this paper presents the syntheses, structures, and magnetic properties of three
end-to-end (EE) azide/cyanate-bridged copper (II) compounds [CuIIL1 (μ1, 3-NCO)] n· 2 n …

Magneto-Structural Correlation Studies and Theoretical Calculations of a Unique Family of Single End-to-End Azide-Bridged NiII4 Cyclic Clusters

S Sasmal, S Hazra, P Kundu, S Majumder… - Inorganic …, 2010 - ACS Publications
The work in this paper aims to portray a complete structural, magnetic, and theoretical
description of two original end-to-end (EE) μ1, 3-azide-bridged, cyclic tetranuclear NiII …