Taking into account the vast arrays of fluorinated motifs known, 11 this review will be limited
to the monofluorination of organic compounds, ie, synthetic methods allowing the …

Over the past decade, the most significant, conceptual advances in the field of fluorination
were enabled most prominently by organo‐and transition‐metal catalysis. The most …

Very few fields in chemistry have shown such a considerable interest as fluoroorganic
chemistry. Fluorine is perhaps the element that has experienced the greatest recent interest …

Die wichtigsten konzeptionellen Fortschritt auf dem Gebiet der Fluorierungen der letzten
zehn Jahre wurden durch die Organo‐und Übergangsmetallkatalyse ermöglicht. Die …

A visible-light-mediated hydrotrifluoromethylation of unactivated alkenes that uses the
Umemoto reagent as the CF3 source and MeOH as the reductant is disclosed. This effective …

Asymmetric catalysis with chiral metal complexes has received considerable attention in
recent years, and its contribution to the art of organic synthesis has become of leading …

For 80 years, the Diels-Alder addition1–3 has been one of the best methods for the
preparation of six-membered carbocycles with control of up to four stereogenic centers in an …

Abstract Copper‐catalyzed Si− H, B− H, P− H, S− H, and N− H insertion reactions of 2, 2, 2‐
trifluoro‐1‐diazoethane and 1‐aryl 2, 2, 2‐trifluorodiazoethanes generated a large number …

Organofluorine compounds 1 have found increasing applications in key industrial fields
such as the pharmaceutical 2 and medicinal chemistry 3 or crop 4 and material sciences, 5 …

We report an enantio‐and diastereoselective, complete hydrogenation of multiply
substituted benzofurans in a one‐pot cascade catalysis. The developed protocol facilitates …