Carbon nitride based materials: more than just a support for single-atom catalysis

GFSR Rocha, MAR da Silva, A Rogolino… - Chemical Society …, 2023 - pubs.rsc.org
Recently, the missing link between homogeneous and heterogeneous catalysis has been
found and it was named single-atom catalysis (SAC). However, the SAC field still faces …

Review of carbon support coordination environments for single metal atom electrocatalysts (SACS)

W Song, C Xiao, J Ding, Z Huang, X Yang… - Advanced …, 2024 - Wiley Online Library
This topical review focuses on the distinct role of carbon support coordination environment
of single‐atom catalysts (SACs) for electrocatalysis. The article begins with an overview of …

Locking effect in metal@ MOF with superior stability for highly chemoselective catalysis

Y Zhong, P Liao, J Kang, Q Liu, S Wang… - Journal of the …, 2023 - ACS Publications
Ultrasmall metal nanoparticles (NPs) show high catalytic activity in heterogeneous catalysis
but are prone to reunion and loss during the catalytic process, resulting in low …

Peripheral-nitrogen effects on the Ru1 centre for highly efficient propane dehydrogenation

Y Zhou, F Wei, H Qi, Y Chai, L Cao, J Lin, Q Wan… - Nature Catalysis, 2022 - nature.com
Single-atom catalysts with uniform metal active sites show potential for selectivity control.
However, their application to high-temperature propane dehydrogenation remains …

Interlayer charge transfer regulates single-atom catalytic activity on electride/graphene 2D heterojunctions

W Li, C Liu, C Gu, JH Choi, S Wang… - Journal of the American …, 2023 - ACS Publications
Single-atom catalysts with structure and activity tunability have attracted significant attention
for energy and environmental applications. Herein we present a first-principles study of …

Altering the spin state of Fe-NC through ligand field modulation of single-atom sites boosts the oxygen reduction reaction

D Xue, P Yuan, S Jiang, Y Wei, Y Zhou, CL Dong… - Nano Energy, 2023 - Elsevier
Atomically dispersed Fe-NC catalysts are the most promising candidates alternatively to Pt-
based catalysts for oxygen reduction reaction (ORR). However, the ORR activity of Fe-N x …

Tuning the CO2 Hydrogenation Selectivity of Rhodium Single‐Atom Catalysts on Zirconium Dioxide with Alkali Ions

S Li, Y Xu, H Wang, B Teng, Q Liu, Q Li… - Angewandte Chemie …, 2023 - Wiley Online Library
Tuning the coordination environments of metal single atoms (M1) in single‐atom catalysts
has shown large impacts on catalytic activity and stability but often barely on selectivity in …

State-of-the-art single-atom catalysts in electrocatalysis: from fundamentals to applications

M Humayun, M Israr, A Khan, M Bououdina - Nano Energy, 2023 - Elsevier
Metal single-atom catalysts are becoming very popular owing to their remarkable and
fascinating atomic-scale utilization efficiency, electrocatalytic activity, and selectivity …

Modulating the Electronic Metal‐Support Interactions in Single‐Atom Pt1−CuO Catalyst for Boosting Acetone Oxidation

Z Jiang, M Tian, M Jing, S Chai, Y Jian… - Angewandte Chemie …, 2022 - Wiley Online Library
The development of highly active single‐atom catalysts (SACs) and identifying their intrinsic
active sites in oxidizing industrial hazardous hydrocarbons are challenging prospects …

Oxygen-bridging Fe, Co dual-metal dimers boost reversible oxygen electrocatalysis for rechargeable Zn–air batteries

Q Zhou, W Xue, X Cui, P Wang, S Zuo, F Mo… - Proceedings of the …, 2024 - pnas.org
Rechargeable zinc–air batteries (ZABs) are regarded as a remarkably promising alternative
to current lithium-ion batteries, addressing the requirements for large-scale high-energy …