Bowls, hoops, and saddles: synthetic approaches to curved aromatic molecules

MA Majewski, M Stępień - Angewandte Chemie International …, 2019 - Wiley Online Library
This review summarizes recent advances in the chemistry of curved aromatic molecules. By
focusing on the key accomplishments of the last decade, we provide a general overview of …

Emerging applications of carbon nanohoops

EJ Leonhardt, R Jasti - Nature Reviews Chemistry, 2019 - nature.com
A cycloparaphenylene can be thought of as the shortest possible cross section of an
armchair carbon nanotube. Although envisioned decades ago, these molecules—also …

Chemical synthesis of carbon nanorings and nanobelts

Y Li, H Kono, T Maekawa, Y Segawa… - Accounts of Materials …, 2021 - ACS Publications
Conspectus The discovery and creation of new forms of carbon have always transformed the
scientific landscape. For example, the discoveries of fullerenes, carbon nanotubes (CNTs) …

[HTML][HTML] Macrocyclization reactions: the importance of conformational, configurational, and template-induced preorganization

V Marti-Centelles, MD Pandey, MI Burguete… - Chemical …, 2015 - ACS Publications
Macrocyclic structures are common synthetic targets in drug discovery,(1, 2) and therefore,
interest in their study is continuously increasing in this field.(3, 4) A classic example is …

Cycloparaphenylenes and related nanohoops

SE Lewis - Chemical Society Reviews, 2015 - pubs.rsc.org
The first synthesis of a cyclic oligophenylene possessing a radial π system was reported in
2008. In the short period that has elapsed since, there has been an ever-increasing level of …

The dynamic, size-dependent properties of [5]–[12] cycloparaphenylenes

ER Darzi, R Jasti - Chemical Society Reviews, 2015 - pubs.rsc.org
[n] Cycloparaphenylenes (or “carbon nanohoops”) are cyclic fragments of carbon nanotubes
that consist of n para linked benzene rings. These strained, all sp2 hybridized macrocycles …

Recent developments in the Suzuki-Miyaura reaction: 2010–2014

I Maluenda, O Navarro - Molecules, 2015 - mdpi.com
The Suzuki-Miyaura reaction (SMR), involving the coupling of an organoboron reagent and
an organic halide or pseudo-halide in the presence of a palladium or nickel catalyst and a …

Design and synthesis of carbon nanotube segments

Y Segawa, A Yagi, K Matsui… - Angewandte Chemie …, 2016 - Wiley Online Library
The selective and predictable synthesis of structurally uniform carbon nanotubes (CNTs)
represents a long‐standing goal in both nanocarbon science and synthetic organic …

Synthesis of armchair and chiral carbon nanobelts

KY Cheung, S Gui, C Deng, H Liang, Z Xia, Z Liu, L Chi… - Chem, 2019 - cell.com
Carbon nanobelts that consist of a loop of fully fused benzene rings are long-standing and
challenging targets of organic synthesis and are key steps toward the ultimate synthesis of …

Initiation of carbon nanotube growth by well-defined carbon nanorings

H Omachi, T Nakayama, E Takahashi, Y Segawa… - Nature …, 2013 - nature.com
Carbon nanotubes (CNTs), tubular molecular entities that consist of sp 2-hybridized carbon
atoms, are currently produced as mixtures that contain tubes of various diameters and …