Transition Metal Catalyzed Cycloisomerizations of 1,n-Allenynes and -Allenenes

C Aubert, L Fensterbank, P Garcia, M Malacria… - Chemical …, 2011 - ACS Publications
Allenes have always fascinated chemists because of the intriguing features of the cumulated
diene function such as the higher reactivity compared to simple alkenes and the peculiar …

Controlled microwave heating in modern organic synthesis: highlights from the 2004–2008 literature

CO Kappe, D Dallinger - Molecular diversity, 2009 - Springer
Direct and rapid heating by microwave irradiation in combination with sealed vessel
processing in many cases enables reactions to be carried out in a fraction of the time …

[图书][B] Microwaves in organic and medicinal chemistry

CO Kappe, A Stadler, D Dallinger - 2012 - books.google.com
Tailored to the needs of medicinal and natural products chemists, the second edition of this
unique handbook brings the contents up to speed, almost doubling the amount of chemical …

Merging [2+2] Cycloaddition with Radical 1,4‐Addition: Metal‐Free Access to Functionalized Cyclobuta[a]naphthalen‐4‐ols

F Liu, JY Wang, P Zhou, G Li, WJ Hao… - Angewandte Chemie …, 2017 - Wiley Online Library
Abstract A metal‐free [2+ 2] cycloaddition and 1, 4‐addition sequence induced by S‐
centered radicals has been achieved by treating benzene‐linked allene‐ynes with …

Towards the optimal screening collection: a synthesis strategy

TE Nielsen, SL Schreiber - Angewandte Chemie International …, 2008 - Wiley Online Library
The development of effective small‐molecule probes and drugs entails at least three stages:
1) a discovery phase, often requiring the synthesis and screening of candidate compounds …

Exploiting [2+ 2] cycloaddition chemistry: achievements with allenes

B Alcaide, P Almendros, C Aragoncillo - Chemical Society Reviews, 2010 - pubs.rsc.org
The allene moiety represents an excellent partner for the [2+ 2] cycloaddition with alkenes
and alkynes, affording the cyclobutane and cyclobutene skeletons in a single step. This …

Microwave enhanced synthesis

S Caddick, R Fitzmaurice - Tetrahedron, 2009 - Elsevier
Microwave technology has become very important in synthesis and it is reasonable to assert
that there are now very few areas of synthetic organic chemistry that have not been shown to …

Allenes and computational chemistry: from bonding situations to reaction mechanisms

E Soriano, I Fernández - Chemical Society Reviews, 2014 - pubs.rsc.org
The present review is focused on the application of computational/theoretical methods to the
wide and rich chemistry of allenes. Special emphasis is made on the interplay and synergy …

Synthesizing allenes today (1982-2006)

KM Brummond, JE DeForrest - Synthesis, 2007 - thieme-connect.com
Allenes have allowed chemists to access a variety of structurally interesting and biologically
active products. The emergence of these unique compounds in organic synthesis is a direct …

Engaging Yne‐Allenes in Cycloaddition Reactions: Recent Developments

JY Wang, WJ Hao, SJ Tu, B Jiang - Chinese Journal of …, 2022 - Wiley Online Library
Comprehensive Summary Yne‐allenes bearing both a C—C triple bond and an allene unit
are a class of focal substrates in organic synthesis, in view of their structure diversity, high …