Transition-metal catalyzed directing group (DG) assisted annulation of inert C–H bonds
leads to the formation of complex molecular frameworks from readily accessible substrates …

In the past decades, an enormous number of reports have been dedicated towards the
synthesis of nitrogen containing heterocycles. This immense interest have emerged owing to …

Satoh–Miura reaction is an important method for extending π‐systems by forging multi‐
substituted benzene rings via double aryl C− H activation and annulation with alkynes …

Abstract The first enantioselective Satoh–Miura‐type reaction is reported. A variety of C− N
axially chiral N‐aryloxindoles have been enantioselectively synthesized by an asymmetric …

Annulations of unsaturated systems through C–H activation represent a powerful tool for
producing multicyclic scaffolds. Having coordinating centers in both annulation partners (a …

Herein, we report the additive-controlled divergent synthesis of tetrasubstituted 1, 3-enynes
and alkynylated 3 H-pyrrolo [1, 2-a] indol-3-ones through rhodium-catalyzed C–H …

The synthesis of N-naphthyl pyrazoles has been realized by the direct three-component
reactions of enaminones, aryl hydrazine hydrochlorides and internal alkynes via Rh (III) …

Twofold C− H annulation of readily available formamides and alkynes without built‐in
chelating groups was achieved. Ni− Al bimetallic catalysis enabled by a bulky BINOL …

Alkynes occupy a prominent role as a coupling partner in the transition metal-catalysed
directed C–H activation reactions. Due to low steric requirements and linear geometry …

Herein we report Cp* Co (III)-catalyzed site-selective (C8)–H olefination and oxyarylation of
quinoline N-oxides with terminal alkynes. The selectivity for C8-olefination and oxyarylation …