Stable cyclic carbenes and related species beyond diaminocarbenes

M Melaimi, M Soleilhavoup… - Angewandte Chemie …, 2010 - Wiley Online Library
The success of homogeneous catalysis can be attributed largely to the development of a
diverse range of ligand frameworks that have been used to tune the behavior of various …

Synthesis and reactions of N‐heterocyclic carbene boranes

DP Curran, A Solovyev… - Angewandte Chemie …, 2011 - Wiley Online Library
Boranes are widely used Lewis acids and N‐heterocyclic carbenes (NHCs) are popular
Lewis bases, so it is remarkable how little was known about their derived complexes until …

Enantioselective alkynylbenzaldehyde cyclizations catalyzed by chiral gold (I) acyclic diaminocarbene complexes containing weak Au–arene interactions

S Handa, LGM Slaughter - Angewandte Chemie International Edition, 2012 - infona.pl
Hold me close: Highly enantioselective catalysis of tandem acetalization/cycloisomerization
reactions of o‐alkynylbenzaldehydes has been achieved using gold complexes of chiral …

Stabile cyclische Carbene und verwandte Spezies jenseits der Diaminocarbene

M Melaimi, M Soleilhavoup, G Bertrand - Angewandte Chemie, 2010 - Wiley Online Library
Abstract Der Erfolg der homogenen Katalyse kann hauptsächlich der Entwicklung einer
breiten Palette von Ligandengerüsten zugeschrieben werden, die vielfach genutzt wurden …

Acyclic diaminocarbenes (ADCs) as a promising alternative to N-heterocyclic carbenes (NHCs) in transition metal catalyzed organic transformations

VP Boyarskiy, KV Luzyanin, VY Kukushkin - Coordination Chemistry …, 2012 - Elsevier
Starting from the first reported application of complexes bearing acyclic diaminocarbene
(ADC) ligands as catalysts ca. 5 years ago, these compounds have been successfully …

A general rhodium‐catalyzed cyanation of aryl and alkenyl boronic acids

P Anbarasan, H Neumann, M Beller - Angewandte Chemie, 2011 - infona.pl
Das CyanierungsmittelN‐Cyan‐N‐phenyl‐p‐toluolsulfonamid ermöglicht die Synthese von
Aryl‐und Alkenylnitrilen in guter Ausbeute und unter milden Bedingungen (siehe Beispiel; …

Acyclic aminocarbenes in catalysis

LGM Slaughter - ACS Catalysis, 2012 - ACS Publications
Acyclic aminocarbenes have received much less attention as ancillary ligands in
homogeneous catalysis compared with their cyclic relatives (ie, N-heterocyclic carbenes …

Synthesis and contemporary applications of platinum group metals complexes with acyclic diaminocarbene ligands

MA Kinzhalov, KV Luzyanin - Russian Journal of Inorganic Chemistry, 2022 - Springer
Complexes of platinum group metals with acyclic diaminocarbene ligands have found
application as transition metal catalysts, photoluminescent materials, chemosensors, and …

Deprotonative metalation of substituted benzenes and heteroaromatics using amino/alkyl mixed lithium–zinc combinations

K Snégaroff, S Komagawa, F Chevallier… - … A European Journal, 2010 - Wiley Online Library
Different homoleptic and heteroleptic lithium–zinc combinations were prepared, and
structural elements obtained on the basis of NMR spectroscopic experiments and DFT …

ADC-based palladium catalysts for aqueous Suzuki–Miyaura cross-coupling exhibit greater activity than the most advantageous catalytic systems

MA Kinzhalov, KV Luzyanin, VP Boyarskiy… - …, 2013 - ACS Publications
The reaction between the equimolar amounts of cis-[PdCl2 (CNR1) 2](R1= cyclohexyl
(Cy)(1), t Bu (2)) and the carbohydrazides R2CONHNH2 (R2= Ph (5), 4-ClC6H4 (6), 3 …