Synthesis of α, β-unsaturated carbonyl compounds by carbonylation reactions

S Zhang, H Neumann, M Beller - Chemical Society Reviews, 2020 - pubs.rsc.org
α, β-Unsaturated carbonyl compounds are key building blocks in organic chemistry. Their
catalytic synthesis has received significant attention during the past decades. Among the …

[图书][B] Applied homogeneous catalysis with organometallic compounds: a comprehensive handbook in four volumes

B Cornils, WA Herrmann, M Beller, R Paciello - 2017 - books.google.com
The completely revised third edition of this four-volume classic is fully updated and now
includes such topics as as CH-activation and multicomponent reactions. It describes the …

Selective palladium-catalyzed carbonylation of alkynes: an atom-economic synthesis of 1, 4-dicarboxylic acid diesters

J Liu, K Dong, R Franke, H Neumann… - Journal of the …, 2018 - ACS Publications
A class of novel diphosphine ligands bearing pyridine substituents was designed and
synthesized for the first time. The resulting palladium complexes of L1 allow for chemo-and …

Room-temperature Pd-catalyzed methoxycarbonylation of terminal alkynes with high branched selectivity enabled by bisphosphine-picolinamide ligand

D Liu, M Ke, T Ru, Y Ning, FE Chen - Chemical Communications, 2022 - pubs.rsc.org
We report the room-temperature Pd-catalyzed methoxy-carbonylation with high branched
selectivity using a new class of bisphosphine-picolinamide ligands. Systematic optimization …

Phosphines in artificial photosynthesis: considering different aspects such as chromophores, water reduction catalysts (WRCs), water oxidation catalysts (WOCs), and …

J Pann, H Roithmeyer, W Viertl, R Pehn… - Sustainable Energy & …, 2019 - pubs.rsc.org
In this review we present the development of mono-, di-, and tetraphosphine ligands for
chromophores and water reduction catalysts (WRCs) in artificial photosynthesis (AP) during …

Mechanism and origin of ligand-controlled chemo-and regioselectivities in palladium-catalyzed methoxycarbonylation of alkynes

L Zhu, LJ Liu, YY Jiang, P Liu, X Fan… - The Journal of …, 2020 - ACS Publications
Pd-catalyzed alkoxycarbonylation of alkynes provided a redox-neutral method to selectively
access branched/linear α, β-unsaturated monoesters and 1, 4-dicarboxylic acid diesters …

[HTML][HTML] Palladium-catalyzed regio-and stereoselective alkoxycarbonylation of unsymmetrical internal alkynes toward α, β-unsaturated succinates

CS Kuai, BH Teng, Y Zhao, XF Wu - Tetrahedron Chem, 2022 - Elsevier
Succinates play a vital role in industry, pharmaceutics, beverage, and cosmetics. A regio-
and stereoselective alkoxycarbonylation of unsymmetrical internal alkynes with alcohols or …

[HTML][HTML] New rigid polycyclic bis (phosphane) for asymmetric catalysis

KM Pietrusiewicz, K Szwaczko, B Mirosław, I Dybała… - Molecules, 2019 - mdpi.com
A simple, highly efficient synthesis of a series of novel chiral non-racemic rigid tetracyclic
phosphorus ligands, applicable in important chemical asymmetric transformations, was …

A direct synthesis of carboxylic acids via platinum-catalysed hydroxycarbonylation of olefins

C Schneider, R Franke, R Jackstell… - Catalysis Science & …, 2021 - pubs.rsc.org
The platinum-catalysed hydroxycarbonylation of olefins is reported for the first time. Using a
combination of PtCl2/2, 2′-bis (tert-butyl (pyridin-2-yl) phosphanyl)-1, 1′-binaphthalene …

Reductive elimination of anhydrides from anionic iodo acetyl carboxylato rhodium complexes

D Hanh Nguyen, N Lassauque… - European Journal of …, 2014 - Wiley Online Library
The first part of this study is devoted to the search for improved and highly efficient synthetic
procedures for the preparation of rhodium carbonyl precursors, and the second part to the …