The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …

While hydrogen plays an ever-increasing role in modern society, nature has utilized
hydrogen since a very long time as an energy carrier and storage molecule. Among the …

This review is a comprehensive survey of the last 10 years of research on ammonia–borane
and amine–borane dehydrogenation mediated by complex metal hydrides (CMHs), within …

A systematic study of the catalyst structure and overall charge for the dehydropolymerization
of H3B· NMeH2 to form N-methyl polyaminoborane is reported using catalysts based upon …

Anionic α‐diimine cobalt complexes, such as [K (thf) 1.5 {(DippBIAN) Co (η4‐cod)}](1; Dipp=
2, 6‐diisopropylphenyl, cod= 1, 5‐cyclooctadiene), catalyze the dehydrogenation of several …

Dehydrocoupling of phosphine-and amine-boranes is reported using an iron (II) β-
diketiminate complex. Dehydrocoupling of amine-boranes is far more facile than the …

A Co (I) complex featuring the electron-rich monoanionic bis (carbene) aryl pincer ligand
(MesCCC)(MesCCC= bis (2, 4, 6-trimethylphenyl-benzimidazol-2-ylidene) …

This study focuses on [FeFe]-hydrogenase and its metallorganic mimics in terms of
electronic and photophysical properties, which can be applied to the electrochemical and/or …

The title complex (t BuPCP) IrH (Cl)(1; t BuPCP= κ3-2, 6-(CH2P t Bu2) 2C6H3) appeared to
be moderately active in NHMe2· BH3 (DMAB) dehydrogenation, allowing the systematic …

Catalytic dehydrocoupling methodologies, whereby dihydrogen is released from a substrate
(or intermolecularly from two substrates) is a mild and efficient method to construct main …