Catalytic partial reduction of N‐heteroarenes with H2 or H [E](E= Si, B‐based) has been a
useful and general method for synthesis of a broad range of dihydropyridines (DHP) and …

The N, N′-chelated conjugated bis-guanidinate (CBG) supported zinc hydride (Zn-1) pre-
catalyzed highly challenging chemoselective mono-hydrosilylation of a wide range of nitriles …

Zinc dihydride complexes supported by bulky N‐heterocyclic carbenes (NHC) are efficient
catalysts in hydroboration reactions. Herein, a set of zinc complexes with an amino‐pyrrolide …

A fluorenyl‐tethered N‐heterocyclic carbene LH (LH=[(Flu) H−(CH2) 2− NHCDipp]) and its
monoanionic version L− are explored in complexation with zinc towards the hydroboration of …

Selective reduction of readily available N-heteroarenes is important in both organic
synthesis and chemical biology. Herein, we describe ligand-controlled regiodivergent …

First-generation ruthenium–indenylidene olefin metathesis complex catalyzes the 1, 2-
hydrosilylation reaction to access dihydroquinoline derivatives with high regioselectivity …

Catalytic hydroboration and hydrosilylation have emerged as promising strategies for the
reduction of unsaturated hydrocarbons and carbonyl compounds, as well as for the …

We report herein a mild stereo‐and regioselective dearomatization of quinolines using the
simple low valent HCo (N2)(PPh3) 3 complex that exhibits labile ligands. Conditions to form …

The conjugated bis-guanidinate (CBG)-stabilized zinc hydride,[{LZnH} 2;(L={(ArNH)(ArN)–
C═ N–C═(NAr)(NHAr)}; Ar= 2, 6-Et2-C6H3)](Zn-1), is shown to be a highly active catalyst …

The reactions of amides [tBu2CarbAr2] MN (SiMe3) 2 (THF)(M= Ca (5), Yb (6)) and
[tBu2CarbAr2] MN (SiMe3) 2 (M= Ca (7), Yb (8)) coordinated by a bulky carbazolyl ligand …