Frontal ring-opening metathesis polymerization (FROMP) is a rapid, low-energy manufacturing reaction that is useful for curing thermosetting materials. FROMP of …
K Tashiro, M Akiyama, K Kashiwagi… - Journal of the American …, 2023 - ACS Publications
Fluoroalkenes are known to be notoriously reluctant substrates for olefin metathesis due to the generation of thermodynamically stable Fischer-type fluorocarbene intermediates, which …
H Sun, T Ibrahim, A Ritacco, K Durkee - ACS Macro Letters, 2023 - ACS Publications
Degradable polymers made via ring-opening metathesis polymerization (ROMP) hold tremendous promise as eco-friendly materials. However, most of the ROMP monomers are …
Commercially available Vince lactam and its derivatives are copolymerized with 2, 3- dihydrofuran (DHF) in a living fashion based on the unique reactivity of Ru Fischer carbene …
A Mandal, I Mandal… - Angewandte Chemie …, 2023 - Wiley Online Library
A catalytic living ring‐opening metathesis copolymerization (ROMP) method is described that relies on a degenerative, reversible and regioselective exchange of propagating Fischer …
Star polymers have attracted considerable attention over the past few years due to their distinctive physical and chemical attributes that are different from conventional linear …
T An, H Ryu, TL Choi - Angewandte Chemie, 2023 - Wiley Online Library
Dihydrofuran (DHF) has recently been gaining significant attention as a comonomer in metathesis polymerization, thanks to its ability to provide the resultant polymer backbones …
SC Leguizamon, K Lyons, NT Monk… - … Applied Materials & …, 2022 - ACS Publications
Thermoset materials comprise a significant proportion of high-performance plastics due to their shape permanence and excellent thermal and mechanical properties. However, these …
Terminal alkynes display high reactivity toward Ru-carbene metathesis catalysts. However, the formation of a less reactive bulky carbene hinders their homopolymerization …