Metal-organic frameworks in Russia: From the synthesis and structure to functional properties and materials

MA Agafonov, EV Alexandrov, NA Artyukhova… - Journal of Structural …, 2022 - Springer
Current research fields of metal-organic frameworks (MOFs), which are being developed in
the last 5-10 years by Russian scientific institutions and universities, are generalized. The …

Single-ion magnetism behaviors in lanthanide (III) based coordination frameworks

Q Wan, M Wakizaka, M Yamashita - Inorganic Chemistry Frontiers, 2023 - pubs.rsc.org
Single-ion magnets (SIMs) and single-molecule magnets (SMMs) are typically made up of
3d and/or 4f complexes that possess significant energy barriers to prevent the spin reversal …

Reversible tuning of luminescence and magnetism in a structurally flexible erbium–anilato MOF

N Monni, JJ Baldoví, V García-López, M Oggianu… - Chemical …, 2022 - pubs.rsc.org
By combining 3, 6-N-ditriazolyl-2, 5-dihydroxy-1, 4-benzoquinone (H2trz2An) with NIR-
emitting ErIII ions, two different 3D neutral polymorphic frameworks (1a and 1b), differing in …

Windmill-like Ln4 Clusters [Ln = Tb(III) and Dy(III)] Bridged by [α-AsW9O33]9– Unit Showing Zero-Field SMM Behavior: Experimental and Theoretical Investigation

S Kapurwan, A Mondal, PK Sahu, S Konar - Inorganic Chemistry, 2022 - ACS Publications
Herein, two polyoxometalate (POM)-ligated tetranuclear rare-earth metal complexes having
the molecular formula [Cs x K24–x {Ln4 (H2O) 8 (α-AsW9O33) 4}]· y H2O {x= 5, y= 20, and …

Assembly of dysprosium (iii) cubanes in a metal–organic framework with an ecu topology and slow magnetic relaxation

D Shao, Y Wan, J Yang, Z Ruan, J Zhu, L Shi - Dalton Transactions, 2023 - pubs.rsc.org
A dysprosium (III) metal–organic framework constructed using dysprosium (III) cubanes as
secondary building units has been reported to exhibit field-induced slow magnetic relaxation …

Significant Control on Zero‐Field Quantum Tunneling of Magnetization in Dysprosium Based Single‐Molecule Magnets via Orientation of the Anilato Ligand

P Kumar Sahu, A Mondal… - Chemistry–A European …, 2023 - Wiley Online Library
Tuning the bridging fashion of anilato ligand in dinuclear DyIII complexes, reveals a sizable
effect on the slow relaxation of magnetization. Combined experimental and theoretical …

Anilato‐Based Coordination Polymers with Slow Relaxation of the Magnetization: Role of the Synthetic Method and Anilato Ligand

S Benmansour, C Pintado‐Zaldo… - … A European Journal, 2024 - Wiley Online Library
We have prepared and characterized three coordination polymers formulated as [Dy2
(C6O4Cl2) 3 (fma) 6]⋅ 4.5 fma (1) and [Dy2 (C6O4X2) 3 (fma) 6]⋅ 4fma⋅ 2H2O with X= Br …

Single molecule magnet features in luminescent lanthanide coordination polymers with heptacoordinate Dy/Yb (iii) ions as nodes

XT Dong, MQ Yu, YB Peng, GX Zhou, G Peng… - Dalton …, 2023 - pubs.rsc.org
Two sets of 1D/2D lanthanide coordination polymers with formulas of Ln (oqa) 3· 2H2O
[Hoqa= 2-(4-oxoquinolin-1 (4H)-yl) acetic acid, Ln= Dy (1), Yb (2)] and Ln (oaa) 2 …

An alkoxyborate-bridging Dy 2 single-molecule magnet with ferromagnetic coupling

YQ Zhou, W Deng, SN Du, YC Chen… - Inorganic Chemistry …, 2024 - pubs.rsc.org
Non-radical bridges capable of coupling Ising-type magnetic anisotropy in a collinear
manner are rather limited in the construction of dinuclear single-molecule magnets (SMMs) …

Tunable SIM properties in a family of 3D anilato-based lanthanide-MOFs

N Monni, S Dey, V García-López, M Oggianu… - Inorganic Chemistry …, 2024 - pubs.rsc.org
By reacting a 3, 6-ditriazolyl-2, 5-dihydroxybenzoquinone (H2trz2An) anilato linker with LnIII
ions (LnIII= Dy, Tb, Ho), two different series of polymorphs, formulated as [Ln2 (trz2An) 3 …