A tetramanganese cluster (Mn4) resides at the active site of photosystem II (PSII) in green
plants and in certain bacteria and algae. It catalyzes the light-driven water oxidation reaction …

The chemistry of manganese has received considerable attention in recent years due to the
fact that manganese is believed to be catalytically active in a variety of metalloenzymes. This …

High oxidation-state molecular compounds or polymeric oxides of Mn or Ce have a wide
range of applications in diverse areas involving inorganic, organic, environmental, and …

A series of complexes with the formula [MnIII/IV2 (μ-O) 2 (L) 2 (X) 2] 3+ have been prepared
in situ from MnIILCl2 precursors by a general preparative method (L= terpy, Cl-terpy, Br …

Abstract Reactions of CeIII (NO3) 3⋅ 6 H2O or (NH4) 2 CeIV (NO3) 6 with Mn‐containing
starting materials result in seven novel polynuclear Ce or Ce/Mn complexes with pivalato …

Polyanion [{Ce (H2O) 2} 2Mn2 (B-α-GeW9O34) 2] 8−(1) constitutes the first example of a
heterometallic 3d− 4f cluster related to the Weakley-type dimeric structure, and it contains an …

Eighteen Mn complexes with N-donor and carboxylate ligands have been synthesized and
characterized. Three Mn complexes among them are new and are reported for the first time …

The use of phosphonic acids in the synthesis of mixed-metal CeMn complexes has led to the
formation of two phosphonate complexes with unusual topologies:[Ce2Mn6O6 (OH) 5 (t …

The trinuclear oxo bridged manganese cluster,[MnIV3O4 (terpy)(terpyO2) 2 (H2O)](S2O8) 2
(5)(terpy= 2, 2′: 2′′, 6′-terpyridine and terpyO2= 2, 2′: 2′′, 6′-terpyridine 1, 1 …

The influence of electrostatic interactions on the free energy of proton coupled electron
transfer in biomimetic oxomanganese complexes inspired by the oxygen-evolving complex …