Synthesis of Statistical Multiblock Copolymers through Chain Shuttling Copolymerization with a Thermomechanical Switch Behavior

A Vittoria, G Urciuoli, S Costanzo, V Ianniello… - …, 2024 - ACS Publications
A high-throughput experimentation (HTE) approach is adopted for the synthesis of a special
class of elastomeric polyolefins with a tailored thermomechanical response …

Molecular Architecture of Multiblock Copolymers Synthesized by the Chain Shuttling Technology

G Urciuoli, O Ruiz de Ballesteros… - … Chemistry and Physics, 2023 - Wiley Online Library
Recent advances in the characterization of ethylene/1‐octene‐based statistical multiblock
copolymers (MBCs) synthesized via chain shuttling copolymerization are illustrated. The …

Effect of Segregation Strength on Mesophase Separation in Statistical Multiblock Copolymers Synthesized through a High-Throughput Experimentation Approach

G Urciuoli, A Vittoria, FD Cannavacciuolo… - …, 2023 - ACS Publications
Ethylene/hex-1-ene (E/H) statistical multiblock copolymers (MBCs) with molecular mass
between 144 and 188 kDa, and segregation strength greater than that of commercially …