3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

Z Chen, B Wang, J Zhang, W Yu, Z Liu… - Organic Chemistry …, 2015 - pubs.rsc.org
Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

Synthesis of Extended π‐Systems through C–H Activation

Y Segawa, T Maekawa, K Itami - … Chemie International Edition, 2015 - Wiley Online Library
Activation of aromatic C H bonds by a transition metal catalyst has received significant
attention in the synthetic chemistry community. In recent years, rapid and site‐selective …

Direct C− H transformation via iron catalysis

CL Sun, BJ Li, ZJ Shi - Chemical Reviews, 2011 - ACS Publications
The development and application of efficient, convenient, selective, and environmentally
benign synthetic methods is highly desirable in organic chemistry. With this requirement …

Transition‐metal‐catalyzed direct arylation of (hetero) arenes by C H bond cleavage

L Ackermann, R Vicente… - Angewandte Chemie …, 2009 - Wiley Online Library
The area of transition‐metal‐catalyzed direct arylation through cleavage of C H bonds has
undergone rapid development in recent years, and is becoming an increasingly viable …

Cross‐Coupling of Heteroarenes by C H Functionalization: Recent Progress towards Direct Arylation and Heteroarylation Reactions Involving Heteroarenes …

R Rossi, F Bellina, M Lessi… - Advanced Synthesis & …, 2014 - Wiley Online Library
In recent years, transition metal‐catalyzed direct (hetero) arylation reactions of heteroarenes
with (hetero) aryl halides and pseudohalides have received significant attention as eco …

The 2‐Pyridyl Problem: Challenging Nucleophiles in Cross‐Coupling Arylations

XAF Cook, A de Gombert, J McKnight… - Angewandte …, 2021 - Wiley Online Library
Azine‐containing biaryls are ubiquitous scaffolds in many areas of chemistry, and efficient
methods for their synthesis are continually desired. Pyridine rings are prominent amongst …

Organocatalysis in cross-coupling: DMEDA-catalyzed direct C− H arylation of unactivated benzene

W Liu, H Cao, H Zhang, H Zhang… - Journal of the …, 2010 - ACS Publications
A striking breakthrough to the frame of traditional cross-couplings/C− H functionalizations
using an organocatalyst remains unprecedented. We uncovered a conceptually different …

Recent advances in using transition-metal-catalyzed C–H functionalization to build fluorescent materials

B Li, AIM Ali, H Ge - Chem, 2020 - cell.com
Organic fluorescent molecules have broad applications in modern technology, such as in
security systems, chemosensors, bioprobes, field-effect transistors, memory devices, organic …

Recent developments in copper-catalyzed reactions of diazo compounds

X Zhao, Y Zhang, J Wang - Chemical Communications, 2012 - pubs.rsc.org
Copper-catalyzed reaction of diazo compounds generates copper carbene intermediates
that undergo diverse transformations. In recent years, the selectivity and efficiency of these …