Beyond the average: spatial and temporal fluctuations in oxide glass-forming systems

KA Kirchner, DR Cassar, ED Zanotto, M Ono… - Chemical …, 2022 - ACS Publications
Atomic structure dictates the performance of all materials systems; the characteristic of
disordered materials is the significance of spatial and temporal fluctuations on composition …

Relaxation and physical aging in network glasses: a review

M Micoulaut - Reports on Progress in Physics, 2016 - iopscience.iop.org
Recent progress in the description of glassy relaxation and aging are reviewed for the wide
class of network-forming materials such as GeO 2, Ge x Se 1− x, silicates (SiO 2–Na 2 O) or …

[图书][B] Glassy materials and disordered solids: An introduction to their statistical mechanics

K Binder, W Kob - 2011 - books.google.com
This book gives a pedagogical introduction to the physics of amorphous solids and related
disordered condensed matter systems. Important concepts from statistical mechanics such …

Topological principles of borosilicate glass chemistry

MM Smedskjaer, JC Mauro… - The Journal of …, 2011 - ACS Publications
Borosilicate glasses display a rich complexity of chemical behavior depending on the details
of their composition and thermal history. Noted for their high chemical durability and thermal …

Composition dependence of glass transition temperature and fragility. I. A topological model incorporating temperature-dependent constraints

PK Gupta, JC Mauro - The Journal of chemical physics, 2009 - pubs.aip.org
We present a topological model for the composition dependence of glass transition
temperature and fragility. Whereas previous topological models are derived for zero …

Composition dependence of glass transition temperature and fragility. II. A topological model of alkali borate liquids

JC Mauro, PK Gupta, RJ Loucks - The Journal of chemical physics, 2009 - pubs.aip.org
Glass transition temperature and fragility are two important properties derived from the
temperature dependence of the shear viscosity of glass-forming melts. While direct …

Quantitative design of glassy materials using temperature-dependent constraint theory

MM Smedskjaer, JC Mauro, S Sen, Y Yue - Chemistry of Materials, 2010 - ACS Publications
The computational design of new materials has long been a “holy grail” within the materials
chemistry community. However, accurate prediction of glass properties from first principles is …

Pressure Raman effects and internal stress in network glasses

F Wang, S Mamedov, P Boolchand, B Goodman… - Physical Review B …, 2005 - APS
Raman scattering from binary Ge x Se 1− x glasses under hydrostatic pressure shows onset
of a steady increase in the frequency of modes of corner-sharing Ge Se 4 tetrahedral units …

[HTML][HTML] Statistical mechanics of glass

JC Mauro, MM Smedskjaer - Journal of non-crystalline solids, 2014 - Elsevier
The field of glass science is quickly maturing from a purely empirical science to one built
upon rigorous fundamental physics. These advancements offer an unprecedented level of …

Atomic scale foundation of temperature-dependent bonding constraints in network glasses and liquids

M Bauchy, M Micoulaut - Journal of Non-Crystalline Solids, 2011 - Elsevier
The behaviour of bonding constraints with temperature is analyzed from an atomic scale
approach (Molecular Dynamics, MD) combined with partial bond angle distributions (PBAD) …