Deformation behavior and amorphization in icosahedral boron-rich ceramics

A Awasthi, G Subhash - Progress in Materials Science, 2020 - Elsevier
Among hard materials, icosahedra-based boron-rich ceramics are only second to diamond-
based structures. This class of ceramics possesses lower density, higher thermal and …

First-principles design of strong solids: Approaches and applications

RF Zhang, SH Zhang, YQ Guo, ZH Fu, D Legut… - Physics Reports, 2019 - Elsevier
In the design of strong solids, especially hard and superhard materials, this review article
attempts to critically cover an extended field of first-principles derived mechanical properties …

Microstructural characterization of boron-rich boron carbide

KY Xie, V Domnich, L Farbaniec, B Chen, K Kuwelkar… - Acta Materialia, 2017 - Elsevier
Boron carbide has a wide range of solubility, but the effects of stoichiometry on its
microstructure and mechanical response are not well understood. In this study, detailed …

Directional amorphization of boron carbide subjected to laser shock compression

S Zhao, B Kad, BA Remington… - Proceedings of the …, 2016 - National Acad Sciences
Solid-state shock-wave propagation is strongly nonequilibrium in nature and hence rate
dependent. Using high-power pulsed-laser-driven shock compression, unprecedented high …

Experimental observations of amorphization in stoichiometric and boron-rich boron carbide

A Chauhan, MC Schaefer, RA Haber, KJ Hemker - Acta Materialia, 2019 - Elsevier
Boron carbide is extremely hard but has been shown to undergo stress-induced
amorphization when subjected to large nonhydrostatic stresses. This localized …

Preparation of dense B4C ceramics by spark plasma sintering of high-purity nanoparticles

P Li, M Ma, Y Wu, X Zhang, Y Chang, Z Zhuge… - Journal of the European …, 2021 - Elsevier
Boron carbide (B 4 C) is an important structural ceramic material, however, the use of this
material is limited by its poor sinterability and low fracture toughness. Nano-sized powders …

In situ observation of fracture along twin boundaries in boron carbide

P Li, Y Bu, L Wang, C Wang, J Huang… - Advanced …, 2023 - Wiley Online Library
The observation of fracture behaviors in perfect and twinned B4C crystals via in situ
transmission electron microscopy (TEM) mechanical testing is reported. The crystal structure …

In search of amorphization-resistant boron carbide

G Subhash, AP Awasthi, C Kunka, P Jannotti… - Scripta Materialia, 2016 - Elsevier
Despite its superior mechanical properties, boron carbide suffers from amorphization, a
pressure-induced phenomenon that disturbs crystalline order and likely reduces shear …

Superstrength through nanotwinning

Q An, WA Goddard III, KY Xie, G Sim, KJ Hemker… - Nano …, 2016 - ACS Publications
The theoretical strength of a material is the minimum stress to deform or fracture the perfect
single crystal material that has no defects. This theoretical strength is considered as an …

Structural and Stress Response of Nanotwinned B13CN under Large Strains

H Liang, D Wang, X Song, Q Guo… - The Journal of Physical …, 2023 - ACS Publications
Boron-rich carbides with icosahedral cages as pivotal structural units, which exhibit high
hardness and low density, have promising industrial applications. However, the insufficient …