Transition-metal-catalyzed C–S, C–Se, and C–Te bond formations via cross-coupling and atom-economic addition reactions. Achievements and challenges

IP Beletskaya, VP Ananikov - Chemical Reviews, 2022 - ACS Publications
In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …

Radicals and Sulfur Dioxide: A Versatile Combination for the Construction of Sulfonyl‐Containing Molecules

K Hofman, NW Liu… - Chemistry–A European …, 2018 - Wiley Online Library
Molecules containing a sulfonyl functionality, such as sulfones, sulfonyl chlorides or
sulfonamides play an important role in organic chemistry and have found widespread …

Recent advances in the catalytic synthesis of arylsulfonyl compounds

D Joseph, MA Idris, J Chen, S Lee - ACS Catalysis, 2021 - ACS Publications
Arylsulfonyl compounds are among the most important compounds in pharmaceutical and
medicinal chemistry. Hence, a wide variety of sulfonylation methods have been reported …

Recent progress and emerging technologies towards a sustainable synthesis of sulfones

S Liang, K Hofman, M Friedrich, J Keller… - …, 2021 - Wiley Online Library
Sulfones play a pivotal role in modern organic chemistry. They are highly versatile building
blocks and find various applications as drugs, agrochemicals, or functional materials …

Recent advances in the sulfonylation of C–H bonds with the insertion of sulfur dioxide

G Qiu, K Zhou, J Wu - Chemical Communications, 2018 - pubs.rsc.org
Recent advances in the sulfonylation of C–H bonds with the insertion of sulfur dioxide are
summarized. Usually, a sulfur dioxide surrogate, DABCO·(SO2) 2, is used, which avoids the …

Cu-catalysed enantioselective radical heteroatomic S–O cross-coupling

YF Cheng, ZL Yu, Y Tian, JR Liu, HT Wen, NC Jiang… - Nature Chemistry, 2023 - nature.com
The transition-metal-catalysed cross-coupling reaction has established itself as one of the
most reliable and practical synthetic tools for the efficient construction of carbon …

Organoselenium compounds: Chemistry and applications in organic synthesis

JM Sonego, SI De Diego, SH Szajnman… - … A European Journal, 2023 - Wiley Online Library
Selenium, originally described as a toxin, turns out to be a crucial trace element for life that
appears as selenocysteine and its dimer, selenocystine. From the point of view of drug …

Synthesis of (E)-Quinoxalinone Oximes through a Multicomponent Reaction under Mild Conditions

J Xu, H Yang, L He, L Huang, J Shen, W Li… - Organic …, 2020 - ACS Publications
Herein, a novel method for the gram-scale synthesis of (E)-quinoxalinone oximes through a
multicomponent reaction under mild conditions is described. Such a transformation was …

Photo-induced cross-dehydrogenative alkylation of heteroarenes with alkanes under aerobic conditions

J Xu, H Cai, J Shen, C Shen, J Wu… - The Journal of Organic …, 2021 - ACS Publications
We report a Minisci-type cross-dehydrogenative alkylation in an aerobic atmosphere using
abundant and inexpensive cerium chloride as a photocatalyst and air as an oxidant. This …

Transition-metal and solvent-free oxidative C–H fluoroalkoxylation of quinoxalinones with fluoroalkyl alcohols

J Xu, H Yang, H Cai, H Bao, W Li, P Zhang - Organic letters, 2019 - ACS Publications
The first example of oxidative C–H fluoroalkoxylation of quinoxalinones with fluoroalkyl
alcohols under transition-metal and solvent-free conditions is described. This approach …