Reactivity of ruthenium (II) and copper (I) complexes that possess anionic heteroatomic ligands: Synthetic exploitation of nucleophilicity and basicity of amido, hydroxo …
TB Gunnoe - European journal of inorganic chemistry, 2007 - Wiley Online Library
The preparation and reactivity of late transition‐metal complexes in low oxidation states with
nondative‐heteroatomic ligands (eg, amido, hydroxo, alkoxo, and aryloxo ligands) are …
nondative‐heteroatomic ligands (eg, amido, hydroxo, alkoxo, and aryloxo ligands) are …
A new generation of π-basic dearomatization agents
JM Keane, WD Harman - Organometallics, 2005 - ACS Publications
A new generation of dearomatizing π-bases having the general form {TpM (L)(π-
acid)}(where Tp= hydridotris (pyrazolyl) borate, M= rhenium, molybdenum, tungsten, L …
acid)}(where Tp= hydridotris (pyrazolyl) borate, M= rhenium, molybdenum, tungsten, L …
Dihapto binding of aromatic molecules by π-basic transition metal complexes: development of alternatives to the {Os (NH3) 5} 2+ fragment
Dihapto-coordination of aromatic ligands by electron-rich transition metals can effectively
dearomatize the bound aromatic molecule. The pentaammineosmium (II) system forms …
dearomatize the bound aromatic molecule. The pentaammineosmium (II) system forms …
Direct photocatalytic C–H functionalization mediated by a molybdenum dioxo complex
CL Baumberger, VZ Valley… - Chemical Communications, 2024 - pubs.rsc.org
Direct photocatalytic C–H activation mediated by MoO2Cl2 (bpy-tBu), a unique photoactive
metal OXO, is presented. The limiting step, reoxidation to the Mo dioxo, is evaluated and …
metal OXO, is presented. The limiting step, reoxidation to the Mo dioxo, is evaluated and …
Charge effects on oxygen atom transfer
SB Seymore, SN Brown - Inorganic Chemistry, 2000 - ACS Publications
The rhenium (V) complex [(HCpz3) ReOCl2]+([1]+), the tris (pyrazolyl) methane analogue of
the known tris (pyrazolyl) borate complex (HBpz3) ReOCl2 (2), has been prepared. The two …
the known tris (pyrazolyl) borate complex (HBpz3) ReOCl2 (2), has been prepared. The two …
Activation of Carbon−Hydrogen Bonds via 1,2-Addition across M−X (X = OH or NH2) Bonds of d6 Transition Metals as a Potential Key Step in Hydrocarbon …
TR Cundari, TV Grimes, TB Gunnoe - Journal of the American …, 2007 - ACS Publications
Recent reports of 1, 2-addition of C− H bonds across Ru− X (X= amido, hydroxo) bonds of
TpRu (PMe3) X fragments {Tp= hydridotris (pyrazolyl) borate} suggest opportunities for the …
TpRu (PMe3) X fragments {Tp= hydridotris (pyrazolyl) borate} suggest opportunities for the …
Phenyl-to-oxo migration in an electrophilic rhenium (VII) dioxo complex
Reaction of (HBpz3) ReO (Ph)(OTf) with oxygen atom donors leads to oxidation of the
phenyl group [HBpz3= hydrotris (1-pyrazolyl) borate, OTf= triflate, OSO2CF3]. Reaction with …
phenyl group [HBpz3= hydrotris (1-pyrazolyl) borate, OTf= triflate, OSO2CF3]. Reaction with …
Basicity of uranyl oxo ligands upon coordination of alkoxides
MP Wilkerson, CJ Burns, HJ Dewey, JM Martin… - Inorganic …, 2000 - ACS Publications
Uranium (VI) alkoxide complexes are prepared via metathesis reactions of [UO2Cl2 (THF) 2]
2 with potassium alkoxides in nonaqueous media. The dark red compound U [OCH2C …
2 with potassium alkoxides in nonaqueous media. The dark red compound U [OCH2C …
Synthesis, Structures, and Redox Properties of Octa(μ3-sulfido)hexarhenium(III) Complexes Having Terminal Pyridine Ligands
T Yoshimura, K Umakoshi, Y Sasaki… - Inorganic …, 1999 - ACS Publications
A series of μ3-sulfido Re− Re bonded octahedral hexarhenium (III) clusters having mixed
chloride− pyridine (py) or− 4-cyanopyridine (cpy) terminal ligands,[Bu4N] 2 [trans …
chloride− pyridine (py) or− 4-cyanopyridine (cpy) terminal ligands,[Bu4N] 2 [trans …
Metal and ligand effects on bonding in group 6 complexes of redox-active amidodiphenoxides
LG Ranis, K Werellapatha, NJ Pietrini… - Inorganic …, 2014 - ACS Publications
Group 6 complexes M (ONO) 2 (M= Cr, Mo, W; ONO= bis (2-oxy-3, 5-di-tert-butylphenyl)
amide) are prepared by the reaction of divalent metal halide precursors with Pb (ONOQ) 2 …
amide) are prepared by the reaction of divalent metal halide precursors with Pb (ONOQ) 2 …