Merging molecular catalysts and metal–organic frameworks for photocatalytic fuel production

PM Stanley, J Haimerl, NB Shustova, RA Fischer… - Nature Chemistry, 2022 - nature.com
In the effort to generate sustainable clean energy from abundant resources such as water
and carbon dioxide, solar fuel production—the combination of solar-light harvesting and the …

Microporous framework membranes for precise molecule/ion separations

H Dou, M Xu, B Wang, Z Zhang, G Wen… - Chemical Society …, 2021 - pubs.rsc.org
Microporous framework membranes such as metal–organic framework (MOF) membranes
and covalent organic framework (COF) membranes are constructed by the controlled growth …

Post-synthetic modifications of metal–organic cages

J Liu, Z Wang, P Cheng, MJ Zaworotko… - Nature Reviews …, 2022 - nature.com
Metal–organic cages (MOCs) are discrete, supramolecular entities that consist of metal
nodes and organic linkers, which can offer solution processability and high porosity …

Permanently microporous metal–organic polyhedra

AJ Gosselin, CA Rowland, ED Bloch - Chemical reviews, 2020 - ACS Publications
As compared to porous network solids, including metal–organic frameworks, covalent–
organic frameworks, porous aromatic frameworks, and zeolites, porous molecular materials …

Zirconium metal–organic cages: synthesis and applications

ESM El-Sayed, YD Yuan, D Zhao… - Accounts of Chemical …, 2022 - ACS Publications
Conspectus For the last two decades, materials scientists have contributed to a growing
library of porous crystalline materials. These synthetic materials are typically extended …

Heterometallic cages: synthesis and applications

LK Moree, LAV Faulkner, JD Crowley - Chemical Society Reviews, 2024 - pubs.rsc.org
High symmetry metallosupramolecular architectures (MSAs) have been exploited for a
range of applications including molecular recognition, catalysis and drug delivery. Recently …

Structural chemistry of giant metal based supramolecules

AV Virovets, E Peresypkina, M Scheer - Chemical Reviews, 2021 - ACS Publications
The review presents a bird-eye view on the state of research in the field of giant
nonbiological discrete metal complexes and ions of nanometer size, which are structurally …

Review on metal–organic framework classification, synthetic approaches, and influencing factors: applications in energy, drug delivery, and wastewater treatment

VF Yusuf, NI Malek, SK Kailasa - ACS omega, 2022 - ACS Publications
Metal ions or clusters that have been bonded with organic linkers to create one-or more-
dimensional structures are referred to as metal–organic frameworks (MOFs). Reticular …

Beyond platonic: how to build metal–organic polyhedra capable of binding low-symmetry, information-rich molecular cargoes

CT McTernan, JA Davies, JR Nitschke - Chemical Reviews, 2022 - ACS Publications
The field of metallosupramolecular chemistry has advanced rapidly in recent years. Much
work in this area has focused on the formation of hollow self-assembled metal-organic …

Supramolecular and molecular capsules, cages and containers

CJT Cox, J Hale, P Molinska, JEM Lewis - Chemical Society Reviews, 2024 - pubs.rsc.org
Stemming from early seminal notions of molecular recognition and encapsulation, three-
dimensional, cavity-containing capsular compounds and assemblies have attracted intense …