Abstract The 3, 3′‐disubstituted oxindole structural motif is a prominent feature in many
alkaloid natural products, which include all kinds of tetrasubstituted carbon stereocenters …

Abstract Nitrogen‐, phosphorus‐, and oxygen‐based ligands with chiral backbones have
been the historic workhorses of asymmetric transition‐metal‐catalyzed reactions. On the …

Rhodium-catalyzed asymmetric arylation (RCAA) reactions provide one of the most
straightforward and powerful ways to introduce aryl fragments in an enantioselective …

Natural products and small molecules inspired by them are enjoying a resurgence of interest
because they intersect biological space effectively and selectively. On account of their …

Chiral monophosphorus ligands are playing an important role for the recent advances in
asymmetric catalysis. This review summarizes the latest progress in various asymmetric …

3, 3-Disubstituted oxindoles are an important family of biologically active heterocycles, and
numerous synthetic methodologies have been developed for their synthesis over past …

Allylic alcohols represent an important and highly versatile class of chiral building blocks for
organic synthesis. This Review summarizes the plethora of methods developed for the …

There is a growing need in organic synthesis for efficient methodologies for the asymmetric
synthesis of quaternary carbon centres. One of the most attractive and straightforward …

Though often perceived as the simple metaphorical hybrid of synthetic inorganic and
organic chemistry, synthetic organometallic chemistry continues to vigorously differentiate …

The success of phosphine-oxazoline ligands (PHOX) inspired the progress in P-oxazoline
ligand families by modifying either the ligand backbone, the electronic and/or steric …