[图书][B] Ligand Design in Metal Chemistry

M Stradiotto, RJ Lundgren - 2016 - Wiley Online Library
Names: Stradiotto, Mark, author.| Lundgren, Rylan, author. Title: Ligand design in metal
chemistry: reactivity and catalysis/[edited by] Mark Stradiotto, Rylan Lundgren. Description …

Lewis pairing and frustration of group 13/15 elements geometrically enforced by (ace) naphthalene, biphenylene and (thio) xanthene backbones

O Sadek, G Bouhadir, D Bourissou - Chemical Society Reviews, 2021 - pubs.rsc.org
The synthesis, structure, and reactivity of mixed group 13/group 15 compounds (E13= B, Al,
Ga, In, Tl; E15= N, P, Sb, Bi) featuring a rigid (ace) naphthalene or (thio) xanthene backbone …

Metal‐Free Phosphorus‐Directed Borylation of C(sp2)−H Bonds

O Sadek, A Le Gac, N Hidalgo… - Angewandte Chemie …, 2022 - Wiley Online Library
Spectacular progress has recently been achieved in transition metal‐catalyzed C− H
borylation of phosphines as well as directed electrophilic C− H borylation. As shown here, P …

Tunable luminescence of bithiophene-based flexible Lewis pairs

Y Cao, JK Nagle, MO Wolf… - Journal of the American …, 2015 - ACS Publications
Bithiophene-based flexible Lewis pairs with P (O) R2 (R= phenyl, isopropyl) and BMes2
(Mes= 2, 4, 6-trimethylphenyl) functionalities are able to toggle between closed, Lewis …

Phosphines and related C–P bonded compounds

DW Allen - 2015 - books.rsc.org
This chapter covers the literature published during 2013 relating to the above area, apart
from a few papers from 2012 in less accessible journals which came to light in Chemical …

A Stable but Highly Reactive Phosphine‐Coordinated Borenium: Metal‐free Dihydrogen Activation and Alkyne 1, 2‐Carboboration

M Devillard, R Brousses, K Miqueu… - Angewandte Chemie …, 2015 - Wiley Online Library
Borenium cations have been found to be valuable analogues of boranes as a result of their
cationic character which imparts high electrophilicity. Herein, we report the synthesis …

Silyl Chalconium Ions: Synthesis, Structure and Application in Hydrodefluorination Reactions

N Kordts, S Künzler, S Rathjen, T Sieling… - … A European Journal, 2017 - Wiley Online Library
The synthesis of two series of silylated chalconium borates, 9 and 10, which are based on
the peri‐naphthyl and peri‐acenaphthyl framework, is reported (chalcogen (Ch): O, S, Se …

Probing Donor–Acceptor Interactions in peri-Substituted Diphenylphosphinoacenaphthyl–Element Dichlorides of Group 13 and 15 Elements

E Hupf, E Lork, S Mebs, L Checinska… - Organometallics, 2014 - ACS Publications
Transmetalation reactions of ArLi with ECl3 (E= Al, P, In, Bi) and ArSnBu3 with ECl3 (E= B,
Ga, Tl, As, Sb) gave rise to the formation of peri-substituted diphenylphosphinoacenaphthyl …

A Phosphine‐Coordinated Boron‐Centered Gomberg‐Type Radical

AJ Rosenthal, M Devillard, K Miqueu… - Angewandte Chemie …, 2015 - Wiley Online Library
The P‐coordinated boryl radical [Ph2P (naphthyl) BMes].(Mes= mesityl) was prepared by
(electro) chemical reduction of the corresponding borenium salt or bromoborane. Electron …

The Phosphinoboration of N‐Heterocycles

SJ Geier, CM Vogels, NR Mellonie… - … A European Journal, 2017 - Wiley Online Library
The addition of phosphinoboronate ester Ph2PBpin (pin= 1, 2‐O2C2Me4)(1) to a number of
different N‐heterocycles has been investigated. Reaction of 1 with pyridine resulted in highly …