Biobased vitrimers: Towards sustainable and adaptable performing polymer materials

MA Lucherelli, A Duval, L Avérous - Progress in Polymer Science, 2022 - Elsevier
In the last decades, Covalent Adaptable Networks (CAN) appeared as an innovative
polymer family, able to bridge the gap between thermoplastics and thermosets. CAN rely on …

Vitrimers: Current research trends and their emerging applications

J Zheng, ZM Png, SH Ng, GX Tham, E Ye, SS Goh… - Materials Today, 2021 - Elsevier
The development of recyclable plastics is a key research focus in today's world due to their
environmental issues, and non-renewability concerns. Recently, vitrimeric materials have …

Recycling and the end of life assessment of fluoropolymers: recent developments, challenges and future trends

B Améduri, H Hori - Chemical Society Reviews, 2023 - pubs.rsc.org
Herein, we present the state of the art technology on the recycling, reuse, thermal
decomposition (by thermolysis, thermal processing, flash pyrolysis, smoldering, open …

Structure–reactivity–property relationships in covalent adaptable networks

V Zhang, B Kang, JV Accardo… - Journal of the American …, 2022 - ACS Publications
Polymer networks built out of dynamic covalent bonds offer the potential to translate the
control and tunability of chemical reactions to macroscopic physical properties. Under …

Adaptable crosslinks in polymeric materials: resolving the intersection of thermoplastics and thermosets

GM Scheutz, JJ Lessard, MB Sims… - Journal of the American …, 2019 - ACS Publications
The classical division of polymeric materials into thermoplastics and thermosets based on
covalent network structure often implies that these categories are distinct and irreconcilable …

Vitrimers: directing chemical reactivity to control material properties

M Guerre, C Taplan, JM Winne, FE Du Prez - Chemical science, 2020 - pubs.rsc.org
The development of more sustainable materials with a prolonged useful lifetime is a key
requirement for a transition towards a more circular economy. However, polymer materials …

Dynamic covalent chemistry in polymer networks: a mechanistic perspective

JM Winne, L Leibler, FE Du Prez - Polymer Chemistry, 2019 - pubs.rsc.org
The incorporation of dynamic covalent linkages within and between polymer chains brings
new properties to classical thermosetting polymer formulations, in particular in terms of …

Vitrimers: Associative dynamic covalent adaptive networks in thermoset polymers

B Krishnakumar, RVSP Sanka, WH Binder… - Chemical Engineering …, 2020 - Elsevier
The vitrimer-thermoset concept represents an important contribution to improve the durability
and recyclability of thermoset-systems. The concept of Associative Dynamic Covalent …

Rheology of vitrimers

F Meng, MO Saed, EM Terentjev - Nature Communications, 2022 - nature.com
We describe the full rheology profile of vitrimers, from small deformation (linear) to large
deformation (non-linear) viscoelastic behaviour, providing concise analytical expressions to …

[HTML][HTML] Rapidly reprocessable, degradable epoxy vitrimer and recyclable carbon fiber reinforced thermoset composites relied on high contents of exchangeable …

H Si, L Zhou, Y Wu, L Song, M Kang, X Zhao… - Composites Part B …, 2020 - Elsevier
With large quantities of waste carbon fiber reinforced polymer (CFRP) composites
generated, the development of recycling routes for CFRP composites have been driven by …