Metal‐organic framework‐based single‐atom electro‐/photocatalysts: Synthesis, energy applications, and opportunities

M Ahmad, J Chen, J Liu, Y Zhang, Z Song… - Carbon …, 2024 - Wiley Online Library
Single‐atom catalysts (SACs) have gained substantial attention because of their exceptional
catalytic properties. However, the high surface energy limits their synthesis, thus creating …

Coordination ring-opening polymerization of cyclic esters: A critical overview of DFT modeling and visualization of the reaction mechanisms

I Nifant'ev, P Ivchenko - Molecules, 2019 - mdpi.com
Ring-opening polymerization (ROP) of cyclic esters (lactones, lactides, cyclic carbonates
and phosphates) is an effective tool to synthesize biocompatible and biodegradable …

Cooperative effects in multimetallic complexes applied in catalysis

R Maity, BS Birenheide, F Breher, B Sarkar - ChemCatChem, 2021 - Wiley Online Library
The field of multimetallic catalysis is rapidly developing and some multimetallic complexes
catalyze organic transformations to yield the desired products in more efficient ways owing …

Theoretical insight into the redox-switchable activity of group 4 metal complexes for the ring-opening polymerization of ε-caprolactone

X Xu, G Luo, Z Hou, PL Diaconescu… - Inorganic Chemistry …, 2020 - pubs.rsc.org
Redox-switchable polymerization has drawn increasing attention, in particular for the ring-
opening polymerization (ROP) of biomass-derived monomers. However, an understanding …

Valence‐variable Catalysts for Redox‐controlled Switchable Ring‐opening Polymerization

B Li, C Hu, X Pang, X Chen - Chemistry–An Asian Journal, 2023 - Wiley Online Library
As a representative class of sustainable polymer materials, biodegradable polymers have
attracted increasing interest in recent years. Despite significant advance of related …

Mechanistic Study on Steric Activity Interplay of Olefin/Polar Monomers for Industrially Selective Late Transition Metal Catalytic Reactions

A Mehmood, A Mahmood, N AlMasoud, A Hassan… - Molecules, 2023 - mdpi.com
A significant issue in developing metal-catalyzed plastic polymer materials is obtaining
distinctive catalytic characteristics to compete with current plastics in industrial commodities …

Theoretical insight into the opposite redox activity of iron complexes toward the ring opening polymerization of lactide and epoxide

X Xu, H Lu, G Luo, X Kang, Y Luo - Inorganic Chemistry Frontiers, 2021 - pubs.rsc.org
The origin of opposite reactivity in the ring-opening polymerizations of lactide (LA) and
cyclohexene oxide (CHO) catalyzed by redox-switchable bis (imino) pyridine iron complexes …

DFT Investigations on the Ring-Opening Polymerization of Trimethylene Carbonate Catalysed by Heterocyclic Nitrogen Bases

M Lalanne-Tisné, A Favrelle-Huret, W Thielemans… - Catalysts, 2022 - mdpi.com
Organocatalysts for polymerization have known a huge interest over the last two decades.
Among them, heterocyclic nitrogen bases are widely used to catalyse the ring-opening …

Hidden Heterometallic Interaction Emerging from Resonant Inelastic X-ray Scattering in Luminescent Tb–Pt Molecules

T Yoshida, A Shabana, DC Izuogu, K Fuku… - The Journal of …, 2022 - ACS Publications
Theoretical calculations are typically utilized for examining intermetallic interactions.
However, to validate the theory, experimental confirmation of the existence of these …

[图书][B] Neuartige mono-und multimetallische Komplexe auf Basis des Ferrocens

B Birenheide - 2022 - books.google.com
Eisenbasierte Sandwich-und Halbsandwichkomplexe erfreuen sich seit Entdeckung des
Ferrocens eines großen Interesses und ihre vielfältigen Eigenschaften lassen sie in …