Knotting matters: orderly molecular entanglements

Z Ashbridge, SDP Fielden, DA Leigh, L Pirvu… - Chemical Society …, 2022 - pubs.rsc.org
Entangling strands in a well-ordered manner can produce useful effects, from shoelaces and
fishing nets to brown paper packages tied up with strings. At the nanoscale, non-crystalline …

The rise and promise of molecular nanotopology

QH Guo, Y Jiao, Y Feng, JF Stoddart - CCS Chemistry, 2021 - chinesechemsoc.org
Molecular nanotopology—a term we coined recently—is a rapidly developing field of
research that is emerging out of the confluence of chemical topology with the mechanical …

The mechanical bond in biological systems

SR Beeren, CT McTernan, F Schaufelberger - Chem, 2023 - cell.com
The field of mechanically interlocked molecules (MIMs) has advanced rapidly in recent
years, with much work focused on their use in materials, sensing, and catalysis. However …

Covalent organic framework embedded with magnetic nanoparticles for MRI and chemo-thermotherapy

F Benyettou, G Das, AR Nair, T Prakasam… - Journal of the …, 2020 - ACS Publications
Nanoscale imine-linked covalent organic frameworks (nCOFs) were first loaded with the
anticancer drug Doxorubicin (Dox), coated with magnetic iron oxide nanoparticles (γ-Fe2O3 …

A molecular endless (74) knot

DA Leigh, JJ Danon, SDP Fielden, JF Lemonnier… - Nature Chemistry, 2021 - nature.com
Current strategies for the synthesis of molecular knots focus on twisting, folding and/or
threading molecular building blocks. Here we report that Zn (ii) or Fe (ii) ions can be used to …

Vernier template synthesis of molecular knots

Z Ashbridge, E Kreidt, L Pirvu, F Schaufelberger… - Science, 2022 - science.org
Molecular knots are often prepared using metal helicates to cross the strands. We found that
coordinatively mismatching oligodentate ligands and metal ions provides a more effective …

Cinquefoil knot possessing dynamic and tunable metal coordination

Q Zhou, X Dong, G Chi, XY Cao, N Zhang… - Journal of the …, 2024 - ACS Publications
While the majority of knots are made from the metal-template approach, the use of
entangled, constrained knotted loops to modulate the coordination of the metal ions remains …

Pumps through the ages

Y Qiu, Y Feng, QH Guo, RD Astumian, JF Stoddart - Chem, 2020 - cell.com
Artificial molecular machines (AMMs) have profoundly enhanced scientists' capability to
manipulate the relative movements of components within molecules. Mechanically …

Distinctive features and challenges in catenane chemistry

HY Au-Yeung, Y Deng - Chemical Science, 2022 - pubs.rsc.org
From being an aesthetic molecular object to a building block for the construction of
molecular machines, catenanes and related mechanically interlocked molecules (MIMs) …

Silk polymers and nanoparticles: a powerful combination for the design of versatile biomaterials

C Belda Marín, V Fitzpatrick, DL Kaplan… - Frontiers in …, 2020 - frontiersin.org
Silk fibroin (SF) is a natural protein largely used in the textile industry but also in
biomedicine, catalysis, and other materials applications. SF is biocompatible …