Beyond the average: spatial and temporal fluctuations in oxide glass-forming systems

KA Kirchner, DR Cassar, ED Zanotto, M Ono… - Chemical …, 2022 - ACS Publications
Atomic structure dictates the performance of all materials systems; the characteristic of
disordered materials is the significance of spatial and temporal fluctuations on composition …

Relaxation and physical aging in network glasses: a review

M Micoulaut - Reports on Progress in Physics, 2016 - iopscience.iop.org
Recent progress in the description of glassy relaxation and aging are reviewed for the wide
class of network-forming materials such as GeO 2, Ge x Se 1− x, silicates (SiO 2–Na 2 O) or …

Rigidity transitions and molecular structure of glasses

DG Georgiev, P Boolchand, M Micoulaut - Physical Review B, 2000 - APS
T-modulated differential scanning calorimetry measurements on bulk As x Se 1− x glasses
show that the glass transition temperature T g (x) variation at x< 0.12 is linear with a slope dT …

Energy landscape and rigidity

GG Naumis - Physical Review E—Statistical, Nonlinear, and Soft …, 2005 - APS
The effects of floppy modes in the thermodynamical properties of a system are studied. From
thermodynamical arguments, we deduce that floppy modes are not at zero frequency and …

Novel forward osmosis membranes engineered with polydopamine/graphene oxide interlayers: synergistic impact of monomer reactivity and hydrophilic interlayers

P Karami, MM Haque Mizan, B Khorshidi… - Industrial & …, 2023 - ACS Publications
In this study, a series of polyamide membranes with improved water permeability and
thermal stability for forward osmosis applications were synthesized with the main objective …

Rigidity transitions in binary Ge–Se glasses and the intermediate phase

P Boolchand, X Feng, WJ Bresser - Journal of Non-Crystalline Solids, 2001 - Elsevier
Raman scattering measurements, undertaken on bulk GexSe1− x glasses at 0< x< 1/3, show
evidence of two rigidity transitions as monitored by compositional trends in corner-sharing …

Correlation between structural and physical properties in Ge–Sb–Se glasses

WH Wei, RP Wang, X Shen, L Fang… - The Journal of …, 2013 - ACS Publications
Three groups of Ge–Sb–Se glasses with compositions Ge x Sb10Se90–x, Ge x Sb15Se85–
x, and Ge x Sb20Se80–x have been systematically studied with the aim of understanding …

On the structural role of boron in borosilicate glasses

M Hubert, AJ Faber - … Chemistry of Glasses-European Journal of …, 2014 - ingentaconnect.com
The outstanding thermal, mechanical and optical properties of borosilicate glasses give
them significant advantages for applications where conventional soda–lime–silica glasses …

BaO Variation Effect on Crystallization Kinetics of SrO-SiO2-B2O3-ZrO2 Glasses

T Walia, K Singh - Silicon, 2023 - Springer
In the present investigation, BaO effect is studied on the crystallization kinetics of (40-x) SrO-
xBaO-45SiO2-10B2O3-ZrO2 (x= 0, 10, 20, 30, 40 mol%) glasses. To understand the …

Nanoscale phase separation effects near and 2.67, and rigidity transitions in chalcogenide glasses

P Boolchand, DG Georgiev… - Comptes …, 2002 - comptes-rendus.academie-sciences …
Nanoscale phase separation effects are of general interest in glass science. Such structural
effects produce usually pronounced changes in glass physical properties which can mask …