Reactivity of azido terpyridine Pd (ii) and Pt (ii) complexes towards 4, 4, 4-trifluoro-2-butynoic acid: structural insight into the triazolato coordination mode

AM Mansour, K Radacki, GAE Mostafa, EA Ali… - RSC …, 2023 - pubs.rsc.org
The mono-and binuclear azido terpyridine square-planar complexes of ionic formulas,[Pd2
(N3) 2L] 2+ and [Pt (N3) L]+(L= 1, 4-bis (2, 2′: 6′, 2′′-terpyridin-4′ yl) benzene) …

Triazolato Pd (II) and Pt (II) complexes of 2, 6-bis (1-ethylbenzimidazol-2′-yl) pyridine formed via catalyst-free [3+ 2] click reactions

AM Mansour, OR Shehab - Inorganica Chimica Acta, 2023 - Elsevier
At the ambient temperature and under catalyst-free conditions, reactions between [MN 3 (L
ET)] PF 6 (M= Pd (II) and Pt (II); L ET= 2, 6-bis (1-ethylbenzimidazol-2′-yl) pyridine) and …

Role of the ancillary ligand in determining the antimicrobial activity of Pd (II) complexes with N^ N^ N-tridentate coligand

AM Mansour, K Radacki, OR Shehab - Polyhedron, 2022 - Elsevier
Abstract Two [PdN 3 L] PF 6 complexes (L= 2, 6-bis (1-ethyl-benzimidazol-2́-yl) pyridine (L
BZ) and 4-(2-pyridyl)-2, 2′: 6′, 2′'-terpyridine (L PY)) underwent catalyst-free 1, 3-dipolar …

Role of the ancillary ligand in controlling the lysozyme affinity and electronic properties of terpyridine fac-Re (CO) 3 complexes

AM Mansour, K Radacki, OR Shehab - Dalton Transactions, 2021 - pubs.rsc.org
The lysozyme binding affinity and the electronic properties of [ReX (CO) 3 (terpy-κ2N1,
N2)](X= Br− and triazolateCOOCH2CH3, CF3) were reported. The triazolate complex was …

C^ N^ N Coordination Accelerates the iClick Reaction of Square-Planar Palladium (II) and Platinum (II) Azido Complexes with Electron-Poor Alkynes and Enables …

K Peng, D Moreth, U Schatzschneider - Organometallics, 2021 - ACS Publications
Organometal azido complexes with a cyclometalating C^ N^ N coligand of the general
formula [M (N3)(phbpy)] with M= Pd (II) or Pt (II) and Hphbpy= 6-phenyl-2, 2′-bipyridine …

Terpyridine based ReX (CO) 3 compounds (X= Br–, N3–and triazolate): Spectroscopic and DFT studies

AM Mansour, K Radacki - Polyhedron, 2021 - Elsevier
Abstract [ReX (CO) 3 (L–k 2 N 1, N 2)](L= 4′-(4-phenyl morpholine)-2, 2′: 6′, 2′'-
terpyridine, X= Br–(1), N 3–(2), and triazolate (3)) complexes were synthesized, and …

Synthesis of Iridium Tetrazolato, Triazolinato, and Triazolato Complexes by [3+ 2] Cycloaddition of Iridium (III) Azido Complexes with Unsaturated Nitriles

I Sánchez-Sordo, J Díez, E Lastra, MP Gamasa - Organometallics, 2019 - ACS Publications
The diazido complexes [Ir (η5-C5Me5)(N3) 2 (PPh3)](1a),[Ir (η5-C5Me5)(N3) 2 {κ (P)-
R2PCH2CH═ CH2}](R= Ph (1b), i Pr (1c)) have been synthesized and their [3+ 2] …

Probing the factors that influence the conformation of a guanidinato ligand in [(η 5-C 5 Me 5) M (NN) X](NN= chelating N, N′, N′′-tri (o-substituted aryl) guanidinate …

R Kumar, R Kishan, JM Thomas… - New Journal of …, 2018 - pubs.rsc.org
Three types of half sandwich complexes, namely,[(η5-Cp*) M (NN) X](Cp*= C5Me5; NN=
chelating N, N′, N′′-tri (o-substituted aryl) guanidinate (1−) ligand; M= Rh/Ir; X= Cl (9 …

Half Sandwich Electron Deficient N,N′,N′′‐Triarylguanidinatoruthenium(II) Complexes: Syntheses, Reactivity Studies, and Structural Aspects

R Kumar, R Ujjval, N Thirupathi - European Journal of Inorganic …, 2019 - Wiley Online Library
Three symmetrical N, N′, N′′‐triarylguanidinatoruthenium (II) complexes,[(η6‐p‐
cymene) RuCl {κ2 (N, N′)((ArN) 2C‐N (H) Ar)}](Ar= 2‐(CF3) C6H4 (1), 4‐(CF3) C6H4 (2) …

[图书][B] iClick reactions as a modular access to palladium (II) and platinum (II) triazolato complexes: Trends in kinetics and biological activity

K Peng - 2020 - search.proquest.com
In the context of this work, important trends in the influence of the metal center, coligand, and
alkyne reaction partner on the iClick reaction of square-planar palladium (II) and platinum (II) …