Rhenium–a tuneable player in tailored hydrogenation catalysis

ML Gothe, KLC Silva, AL Figueredo… - European Journal of …, 2021 - Wiley Online Library
Although rhenium may not be the most common choice of active species in catalysis, it has
been reported as a highly active and selective catalyst over a wide range of reactions. Its …

Recent developments of heterogeneous catalysts for hydrogenation of carboxylic acids to their corresponding alcohols

M Tamura, Y Nakagawa… - Asian Journal of Organic …, 2020 - Wiley Online Library
Hydrogenation of carboxylic acids is an important organic reaction for the synthesis of
alcohols, aldehydes, alkanes, and so on. Selective hydrogenation of carboxylic acids to …

Insights into the Influence of ZrO2 Crystal Structures on Methyl Laurate Hydrogenation over Co/ZrO2 Catalysts

Y Zhou, L Liu, G Li, C Hu - Acs Catalysis, 2021 - ACS Publications
Six kinds of ZrO2 supports (ZR X, X= 1–6) with different crystal structures (monoclinic ZrO2:
m-ZrO2; tetragonal ZrO2: t-ZrO2; and mixed-phase of monoclinic and tetragonal ZrO2: mix …

[HTML][HTML] Hydrogenation of levulinic acid to γ-valerolactone over Fe-Re/TiO2 catalysts

X Huang, K Liu, WL Vrijburg, X Ouyang… - Applied Catalysis B …, 2020 - Elsevier
Hydrogenation of levulinic acid to γ-valerolactone is a key reaction in the valorization of
carbohydrates to renewable fuels and chemicals. State-of-the-art catalysts are based on …

Low-Temperature Hydrogenation of CO2 to Methanol over Heterogeneous TiO2-Supported Re Catalysts

KW Ting, T Toyao, SMAH Siddiki, K Shimizu - ACS Catalysis, 2019 - ACS Publications
Hydrogenation of carbon dioxide (CO2) to methanol (MeOH) is an effective strategy for CO2
utilization. Because of a low equilibrium conversion of CO2 to MeOH at high temperature …

Activation of Carbonyl Groups via Weak Interactions in Pt/COF/SiO2 Catalyzed Selective Hydrogenation

X Liu, M Wang, X Ren, M Guo, C Li, H Li, Q Yang - ACS Catalysis, 2022 - ACS Publications
Biocatalysts selectively activate chemical bonds via weak interactions; however, this
remains a significant barrier for artificial catalysts. Herein, we report a biomimetic …

Selective hydrogenation of 5-hydroxymethylfurfural and its acetal with 1, 3-propanediol to 2, 5-bis (hydroxymethyl) furan using supported rhenium-promoted nickel …

JJ Wiesfeld, M Kim, K Nakajima, EJM Hensen - Green chemistry, 2020 - pubs.rsc.org
The high reactivity of the formyl group of 5-hydroxymethylfurfural (5-HMF) is problematic,
because it leads to undesired oligomerization reactions. This is usually countered by …

Selective hydrogenation of carboxylic acids to alcohols or alkanes employing a heterogeneous catalyst

J Ullrich, B Breit - ACS Catalysis, 2018 - ACS Publications
The chemoselective hydrogenation of carboxylic acids to either alcohols or alkanes is
reported, employing a heterogeneous bimetallic catalyst consisting of rhenium and …

Rhenium‐Loaded TiO2: A Highly Versatile and Chemoselective Catalyst for the Hydrogenation of Carboxylic Acid Derivatives and the N‐Methylation of Amines Using H2 and …

T Toyao, SMAH Siddiki, Y Morita… - … A European Journal, 2017 - Wiley Online Library
Herein, we report a heterogeneous TiO2‐supported Re catalyst (Re/TiO2) that promotes
various selective hydrogenation reactions, which includes the hydrogenation of esters to …

Efficient hydrogenation of stearic acid over carbon coated NiFe catalyst

X Kong, Z Fang, X Bao, Z Wang, S Mao, Y Wang - Journal of Catalysis, 2018 - Elsevier
Fatty alcohols are widely used as detergents, but the large-scale synthesis still involves
serious environmental pollution due to the use of toxic Cr-containing catalysts. Herein, a …