Abstract Transition‐metal catalyzed intermolecular 1, 2‐diarylation of electronically
unactivated alkenes has emerged as an extensive research topic in organic synthesis …

Difunctionalization of olefins offers an attractive approach to access complex chiral
structures. Reported herein is the design of N-protected O-allylhydroxyamines as …

Alcohols and epoxides are arguably ideal electrophiles for the Friedel-Crafts alkylation,
since they are widely available, require no pre-activation, and produce no stoichiometric …

An alcohol-directed, nickel-catalyzed three-component umpolung carboamination of
unactivated alkenes with aryl/alkenylboronic esters and electrophilic aminating reagents is …

An asymmetric 1, 2-dicarbofunctionalization of unactivated alkenes with aryl iodides and
aryl/alkenylboronic esters under nickel/bioxazoline catalysis is disclosed. A wide array of …

Few methods have been reported for intermolecular arylamination of alkenes, which could
provide direct access to important arylethylamine scaffolds. Herein, we report an …

A plethora of drug molecules and agrochemicals contain the sulfonamide functional group.
However, sulfonamides are seldom viewed as synthetically useful functional groups. To …

A multi-component approach to structurally complex organosulfur products is described via
the nickel-catalyzed 1, 2-carbosulfenylation of unactivated alkenes with organoboron …

We disclose a Ni‐catalyzed regioselective dialkylation reaction of alkenylarenes with α‐
halocarbonyls and alkylzinc reagents. The reaction produces γ‐arylated alkanecarbonyl …

The construction of Csp3–Csp3 bonds through Negishi-type reactions using alkylzinc
reagents as the pronucleophiles is of great importance for the synthesis of pharmaceuticals …