A quarter-century long story of bis (alkyl) rare-earth (III) complexes

AA Trifonov, DM Lyubov - Coordination Chemistry Reviews, 2017 - Elsevier
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Recent progress in the chemistry of metal amidinates and guanidinates: syntheses, catalysis and materials

FT Edelmann - Advances in organometallic chemistry, 2013 - Elsevier
This review provides a comprehensive overview of the most recent progress in chemistry
and applications of metal complexes containing heteroallylic ligands such as amidinates …

Stabilization of calcium hydride complexes by fine tuning of amidinate ligands

A Causero, G Ballmann, J Pahl, H Zijlstra… - …, 2016 - ACS Publications
A range of symmetric amidinate ligands RAmAr (R is backbone substituent, Ar is N
substituent) have been investigated for their ability to stabilize calcium hydride complexes of …

Relativistic spin–orbit heavy atom on the light atom NMR chemical shifts: general trends across the periodic table explained

J Vícha, S Komorovsky, M Repisky… - Journal of Chemical …, 2018 - ACS Publications
The importance of relativistic effects on the NMR parameters in heavy-atom (HA)
compounds, particularly the SO-HALA (Spin–Orbit Heavy Atom on the Light Atom) effect on …

Amido Ln (II) Complexes Coordinated by Bi-and Tridentate Amidinate Ligands: Nonconventional Coordination Modes of Amidinate Ligands and Catalytic Activity in …

IV Basalov, OS Yurova, AV Cherkasov… - Inorganic …, 2016 - ACS Publications
Heteroleptic Ln (II) and Ca (II) amides [t BuC (NC6H3-i Pr2-2, 6) 2] MN (SiMe3) 2 (THF)(M=
Yb (1Yb), Ca (1Ca)),[2-MeOC6H4NC (t Bu) N (C6H3-i Pr2-2, 6)] LnN (SiMe3) 2 (THF)(Ln …

CO reduction by calcium and ytterbium hydride complexes with a bulky monodentate carbazolyl ligand

A Hinz, L Winkler, X Sun - Chemical Communications, 2024 - pubs.rsc.org
The bulky monodentate carbazolyl ligand 1, 8-bis (3, 5-ditertbutylphenyl)-3, 6-
ditertbutylcarbazole (dtbpCbz) was employed in the synthesis of monomeric heteroleptic …

Divalent heteroleptic ytterbium complexes–effective catalysts for intermolecular styrene hydrophosphination and hydroamination

IV Basalov, SC Rosca, DM Lyubov… - Inorganic …, 2014 - ACS Publications
New heteroleptic Yb (II)–amide species supported by amidinate and 1, 3, 6, 8-tetra-tert-
butylcarbazol-9-yl ligands [2-MeOC6H4NC (t Bu) N (C6H3-i Pr2-2, 6)] YbN (SiMe3) 2 …

N‐Heterocyclic Carbene–Ytterbium Amide as a Recyclable Homogeneous Precatalyst for Hydrophosphination of Alkenes and Alkynes

J Yuan, H Hu, C Cui - Chemistry–A European Journal, 2016 - Wiley Online Library
The N‐heterocyclic carbene–ytterbium (II) amides (NHC) 2Yb [N (SiMe3) 2] 2 (1: NHC: 1, 3,
4, 5‐tetramethylimidazo‐2‐ylidene (IMe4); 2: NHC: 1, 3‐diisopropyl‐4, 5‐dimethylimidazol …

Ln (II) and Ca (II) NC sp3 N pincer type diarylmethanido complexes–promising catalysts for C–C and C–E (E= Si, P, N, S) bond formation

DO Khristolyubov, DM Lyubov, AS Shavyrin… - Inorganic Chemistry …, 2020 - pubs.rsc.org
Ln (II)(Ln= Yb, Sm) and Ca (II)[NCsp3N] pincer type diarylmethanido complexes [2, 2′-(4-
MeC6H3NMe2) 2CH] 2M (M= Yb (2), Sm (3), Ca (4)) coordinated by a tridentate …

Reversible hydrosilane addition to pyridines enabled by low-coordinate Ca (ii) and Yb (ii) hydrides

AN Selikhov, MA Bogachev, YV Nelyubina… - Inorganic Chemistry …, 2024 - pubs.rsc.org
The reactions of amides [tBu2CarbAr2] MN (SiMe3) 2 (THF)(M= Ca (5), Yb (6)) and
[tBu2CarbAr2] MN (SiMe3) 2 (M= Ca (7), Yb (8)) coordinated by a bulky carbazolyl ligand …