Activation of C− H bonds by metal complexes

AE Shilov, GB Shul'pin - Chemical Reviews, 1997 - ACS Publications
Hydrocarbons, especially saturated hydrocarbons (alkanes), are the main constituents of oil
and natural gas, the feedstocks for chemical industry. Therefore, it is obvious that …

Organic polyvalent iodine compounds

PJ Stang, VV Zhdankin - Chemical reviews, 1996 - ACS Publications
Iodine was first isolated from the ash of seaweed by the industrial chemist B. Courtois in
1811 and named by JL Gay Lussac in 1813. Its name derives from the Greek term “violet …

Selectivity in the chemistry of oxygen-centered radicals-the formation of carbon-oxygen bonds

J Hartung, T Gottwald, K Špehar - Synthesis, 2002 - thieme-connect.com
In recent years, powerful new methods for the generation of alkoxyl radicals under mild and
neutral conditions have been developed. This progress has led to a thorough investigation …

Allylic oxidation and epoxidation of cycloalkenes by iodosylbenzene catalysed by iron (III) and manganese (III) tetra (dichlorophenyl) porphyrin: the marked influence …

AJ Appleton, S Evans, JRL Smith - Journal of the Chemical Society …, 1996 - pubs.rsc.org
Five cis-cycloalkenes, with ring sizes 5, 6, 7, 8 and 10, and a cis–trans mixture of
cyclododecene have been oxidised by iodosylbenzene using iron (III) or manganese (III) …

Hydrocarbon oxidation with iodosylbenzene catalysed by the sterically hindered iron (III) 5-(pentafluorophenyl)-10, 15, 20-tris (2, 6-dichlorophenyl) porphyrin in …

MD Assis, JRL Smith - Journal of the Chemical Society, Perkin …, 1998 - pubs.rsc.org
Iron (III) 5-(pentafluorophenyl)-10, 15, 20-tris (2, 6-dichlorophenyl) porphyrin has been
synthesised and used to catalyse hydrocarbon oxidation by iodosylbenzene. In …

Co and Mn impregnated MCM-41: their applications to vapour phase oxidation of isopropylbenzene

S Vetrivel, A Pandurangan - Journal of Molecular Catalysis A: Chemical, 2005 - Elsevier
The mesoporous molecular sieves Si-MCM-41 and Al-MCM-41 (Si/Al= 99) were synthesized
and their structures were elucidated by XRD, N2-adsorption isotherm and TG-DTA …

Novel Mn (III) chlorins as versatile catalysts for oxyfunctionalisation of hydrocarbons under homogeneous conditions

FS Vinhado, MEF Gandini, Y Iamamoto… - Journal of Molecular …, 2005 - Elsevier
The novel fluorinated metallochlorin 5, 10, 15, 20-tetrakis (pentafluorophenyl)-tetrahydro-1H-
N-methyl-pyrrolo [3, 4-b]-porphyrinato manganese (III), Mn (chlor)-1, and its methylated …

Manganese porphyrins/mesoporous amberlyst 15 nanocomposites: Robust biomimetic catalysts for aqueous oxidation of olefins

M Malek‐mohammadi… - Applied …, 2023 - Wiley Online Library
In this study, the manganese complexes of N‐methylated meso‐tetra (2‐, 3‐, or 4 pyridyl)
porphyrins, immobilized into the pores of the sodium salt of mesoporous amberlyst 15 …

Origin of the Oxygen Atom in C− H Bond Oxidations Catalyzed by a Water-Soluble Metalloporphyrin

RJ Balahura, A Sorokin, J Bernadou… - Inorganic …, 1997 - ACS Publications
The monopersulfate oxidation of 4-isopropylbenzoic acid performed in H218O and
catalyzed by a water-soluble metalloporphyrin indicated that half of the oxygen atoms …

Axial base‐controlled catalytic activity, oxidative stability and product selectivity of water‐insoluble manganese and iron porphyrins for oxidation of styrenes in water …

S Zakavi, A Hashemi‐Amiri… - Applied Organometallic …, 2018 - Wiley Online Library
A series of water‐insoluble iron (III) and manganese (III) porphyrins, FeT (2‐CH3) PPCl, FeT
(4‐OCH3) PPCl, FeT (2‐Cl) PPCl, FeTPPCl, MnT (2‐CH3) PPOAc, MnT (4‐OCH3) PPOAc …