Frontal polymerizations: from chemical perspectives to macroscopic properties and applications

BA Suslick, J Hemmer, BR Groce, KJ Stawiasz… - Chemical …, 2023 - ACS Publications
The synthesis and processing of most thermoplastics and thermoset polymeric materials rely
on energy-inefficient and environmentally burdensome manufacturing methods. Frontal …

New horizons in cationic photopolymerization

M Sangermano, I Roppolo, A Chiappone - Polymers, 2018 - mdpi.com
In this review, we report some recent advances and new horizons in UV-induced cationic
photopolymerization. In particular, after a brief introduction on the discovery and affirmation …

Evaluation and control of thiol–ene/thiol–epoxy hybrid networks

JA Carioscia, JW Stansbury, CN Bowman - Polymer, 2007 - Elsevier
The development of thiol–ene/thiol–epoxy hybrid networks offers the advantage of tailorable
polymerization kinetics while producing a highly crosslinked, high Tg polymer that has …

Frontal ring-opening metathesis polymerization of dicyclopentadiene

A Mariani, S Fiori, Y Chekanov, JA Pojman - Macromolecules, 2001 - ACS Publications
Introduction. Frontal polymerization entails the conversion of a monomer into a polymer via a
localized exothermic reaction zone that propagates through the coupling of thermal diffusion …

UV-induced frontal polymerization of multifunctional (meth) acrylates

C Nason, T Roper, C Hoyle, JA Pojman - Macromolecules, 2005 - ACS Publications
Photoinduced frontal polymerization was performed on a variety of multifunctional (meth)
acrylates, and evaluation of the effect of monomer structure on the ability to sustain a …

UV‐ignited frontal polymerization of an epoxy resin

A Mariani, S Bidali, S Fiori… - Journal of Polymer …, 2004 - Wiley Online Library
By combining frontal polymerization and radical‐induced cationic polymerization, it was
possible to cure thick samples of an epoxy monomer bleached by UV light. The effect of the …

Tuning the swelling and rheological attributes of bentonite clay modified starch grafted polyacrylic acid based hydrogel

SD Chaudhuri, A Mandal, A Dey, D Chakrabarty - Applied Clay Science, 2020 - Elsevier
Bentonite clay is used to tune the swelling, stimuli responsiveness (sorption and thermal)
and the rheological characteristics of starch grafted polyacrylic acid based hydrogel. Here …

Frontal polymerization synthesis of temperature-sensitive hydrogels

RP Washington, O Steinbock - Journal of the American Chemical …, 2001 - ACS Publications
The study of hydrogels and their response to external environment is of special interest
because of their potential as drug delivery systems, 1, 2 actuators, 3 and separation devices …

First synthesis of a polyurethane by frontal polymerization

S Fiori, A Mariani, L Ricco, S Russo - Macromolecules, 2003 - ACS Publications
The first synthesis of a polyurethane by frontal polymerization has been successfully carried
out. Namely, the two reactants (1, 6-hexamethylene diisocyanate and ethylene glycol) and …

Starch as a reinforcement agent for poly (ionic liquid) hydrogels from deep eutectic solvent via frontal polymerization

Y Chen, S Li, S Yan - Carbohydrate Polymers, 2021 - Elsevier
For the first time, conductive starch/poly (ionic liquid) hydrogels from a polymerizable deep
eutectic solvent (DES) by frontal polymerization (FP) were reported. The solubility and …