We report the design and synthesis of cobalt complexes of L2X-type ligands for olefin
hydroboration guided by the consideration of catalyst stability. Among the series of PCP …

Here, we describe the formation and use of silyl cobalt (III) dihydride complexes as powerful
catalysts for the hydrosilylation of a variety of imines starting from a low-valent well-defined …

A cobalt‐catalyzed addition of hydrosilanes to unsaturated carbon‐oxygen bonds has been
developed, relying on complexes featuring easily accessible and inexpensive PNP‐type …

Organo-silanes, germanes, and stannanes are considered to be conducive to the
development of cross-coupling reactions because they are stable, nontoxic, and easy to …

The cobalt-silyl complexes [Co (H)(SiHPh2)(CyPNP)] and [Co (SiHPh2)(CyPNP)](CyPNP=
anion of 2, 5-bis (dicyclohexylphosphinomethyl) pyrrole) have been prepared by reactions of …

We describe an efficient regio-and chemoselective dearomatization of N-heteroarenes using
hydrido-cobalt catalysts. Reactions were performed under mild conditions on a wide range …

In order to study the effects of silylene ligands on the catalytic activity of carbonyl
hydrosilylation catalyzed by cobalt phosphine complexes, readily available model catalysts …

Despite the utility of Si–Si bonds, there are relatively few examples of Si–Si bond formation
by base metals. In this work, a four-coordinate iron complex,(PNNP) FeII, is shown to …

This study focuses on the stoichiometric reactions of {2, 6-(i Pr2PO) 2C6H3} Co (PMe3) 2
with terminal alkynes, thiols, and tin hydrides as part of an effort to develop catalytic, two …

The selective conversion of unsaturated compounds has emerged as a crucial method in
chemical synthesis, enabling the synthesis of functional organic molecules. In recent …