Advancements in Novel Mechano-Rheological Probes for Studying Glassy Dynamics in Nanoconfined Thin Polymer Films

M Madhusudanan, M Chowdhury - ACS Polymers Au, 2024 - ACS Publications
The nanoconfinement effects of glassy polymer thin films on their thermal and mechanical
properties have been investigated thoroughly, especially with an emphasis on its altered …

A direct quantitative measure of surface mobility in a glassy polymer

Y Chai, T Salez, JD McGraw, M Benzaquen… - Science, 2014 - science.org
Thin polymer films have striking dynamical properties that differ from their bulk counterparts.
With the simple geometry of a stepped polymer film on a substrate, we probe mobility above …

Thermocapillary approaches to the deliberate patterning of polymers

JP Singer - Journal of Polymer Science Part B: Polymer …, 2017 - Wiley Online Library
The phenomenon of thermocapillarity, the response of fluids to thermal gradients due to
thermal alteration of their surface tension, was first reported over a century ago. Since then …

Invariant fast diffusion on the surfaces of ultrastable and aged molecular glasses

Y Zhang, Z Fakhraai - Physical review letters, 2017 - APS
Surface diffusion of molecular glasses is found to be orders of magnitude faster than bulk
diffusion, with a stronger dependence on the molecular size and intermolecular interactions …

Deformation and relaxation of viscous thin films under bouncing drops

S Lakshman, W Tewes, K Harth, JH Snoeijer… - Journal of Fluid …, 2021 - cambridge.org
Thin, viscous liquid films subjected to impact events can deform. Here we investigate free-
surface oil-film deformations that arise owing to the build up of air under the impacting and …

Beyond Tanner's Law: Crossover between Spreading Regimes of a Viscous Droplet<? format?> on an Identical Film

SL Cormier, JD McGraw, T Salez, E Raphaël… - Physical review …, 2012 - APS
We present results on the leveling of polymer microdroplets on thin films prepared from the
same material. In particular, we explore the crossover from a droplet spreading on an …

Capillary levelling of a cylindrical hole in a viscous film

M Backholm, M Benzaquen, T Salez, E Raphaël… - Soft Matter, 2014 - pubs.rsc.org
The capillary levelling of cylindrical holes in viscous polystyrene films was studied using
atomic force microscopy as well as quantitative analytical scaling arguments based on thin …

Using tobacco mosaic virus to probe enhanced surface diffusion of molecular glasses

Y Zhang, R Potter, W Zhang, Z Fakhraai - Soft Matter, 2016 - pubs.rsc.org
Recent studies have shown that diffusion on the surface of organic glasses can be many
orders of magnitude faster than bulk diffusion. Developing new probes that can readily …

Slip-mediated dewetting of polymer microdroplets

JD McGraw, TS Chan, S Maurer… - Proceedings of the …, 2016 - National Acad Sciences
Classical hydrodynamic models predict that infinite work is required to move a three-phase
contact line, defined here as the line where a liquid/vapor interface intersects a solid surface …

Numerical solutions of thin-film equations for polymer flows

T Salez, JD McGraw, SL Cormier, O Bäumchen… - The European Physical …, 2012 - Springer
We report on the numerical implementation of thin-film equations that describe the capillary-
driven evolution of viscous films, in two-dimensional configurations. After recalling the …