The dihydrogen bond an interaction between a transition-metal or main-group hydride (M
H) and a protic hydrogen moiety (H X) is arguably the most intriguing type of hydrogen …

Water and ion dynamics in concentrated LiCl solutions were studied using ultrafast 2D IR
spectroscopy with the methyl thiocyanate (MeSCN) CN stretch as the vibrational probe. The …

Aqueous proton transport involves the ultrafast interconversion of hydrated proton species
that are closely linked to the hydrogen bond dynamics of water, which has been a long …

Many of water's remarkable properties arise from its tendency to form an intricate and robust
hydrogen bond network. Understanding the dynamics that govern this network is …

The water confined in the hydrophilic domains of Nafion fuel cell membranes is central to its
primary function of ion transport. Water dynamics are intimately linked to proton transfer and …

The dynamic nature of hydrogen bonding between a molecular anion, selenocyanate
(SeCN–), and water in aqueous solution (D2O) is addressed using FT-IR spectroscopy, two …

The borohydride ion, BH4–, is an essential reducing agent in many technological processes,
yet its full understanding has been elusive, because of at least two significant challenges …

The ultrafast dynamics of concentrated aqueous solutions of the salt lithium bistriflimide and
ionic liquid (IL) 1-ethyl-3-methylimidazolium bistriflimide was studied using two-dimensional …

Water behavior in various natural and manufactured settings is influenced by confinement in
organic or inorganic frameworks and the presence of solutes. Here, the effects on dynamics …

The asymmetric stretch of the carboxylate group located near 1560 cm− 1 in solutions of
sodium acetate in water and 6M sodium chloride was investigated by linear and two …