Click chemistry strategies for the accelerated synthesis of functional macromolecules

Z Geng, JJ Shin, Y Xi, CJ Hawker - Journal of Polymer Science, 2021 - Wiley Online Library
Click chemistry is one of the most powerful strategies for constructing polymeric soft
materials with precise control over architecture and functionality. In this review, we provide a …

Rapid ordering of block copolymer thin films

PW Majewski, KG Yager - Journal of Physics: Condensed Matter, 2016 - iopscience.iop.org
Block-copolymers self-assemble into diverse morphologies, where nanoscale order can be
finely tuned via block architecture and processing conditions. However, the ultimate usage …

Mimicking biological stress–strain behaviour with synthetic elastomers

M Vatankhah-Varnosfaderani, WFM Daniel… - Nature, 2017 - nature.com
Despite the versatility of synthetic chemistry, certain combinations of mechanical softness,
strength, and toughness can be difficult to achieve in a single material. These combinations …

High χ–Low N Block Polymers: How Far Can We Go?

C Sinturel, FS Bates, MA Hillmyer - 2015 - ACS Publications
Block polymers incorporating highly incompatible segments are termed “high χ” polymers,
where χ is the Flory–Huggins interaction parameter. These materials have attracted a great …

Synthesis and self-assembly of discrete dimethylsiloxane–lactic acid diblock co-oligomers: the dononacontamer and its shorter homologues

B van Genabeek, BFM de Waal… - Journal of the …, 2016 - ACS Publications
Most of the theoretical and computational descriptions of the phase behavior of block
copolymers describe the chain ensembles of perfect and uniform polymers. In contrast …

Fabrication of sub-3 nm feature size based on block copolymer self-assembly for next-generation nanolithography

J Kwak, AK Mishra, J Lee, KS Lee, C Choi… - …, 2017 - ACS Publications
For ultrahigh-density storage media and D-RAM, the feature size of lithography should be
much reduced (say less than 10 nm). Though some research groups reported feature size of …

Directed self-assembly and pattern transfer of five nanometer block copolymer lamellae

AP Lane, XM Yang, MJ Maher, G Blachut, Y Asano… - ACS …, 2017 - ACS Publications
The directed self-assembly (DSA) and pattern transfer of poly (5-vinyl-1, 3-benzodioxole-
block-pentamethyldisilylstyrene)(PVBD-b-PDSS) is reported. Lamellae-forming PVBD-b …

Designing high χ copolymer materials for nanotechnology applications: A systematic bulk vs. thin films approach

PP Angelopoulou, I Moutsios, GM Manesi… - Progress in Polymer …, 2022 - Elsevier
This review article discusses the origins of self-assembly behavior of linear and non-linear
block co-and terpolymers and their application towards the fabrication of high-resolution …

Current status and outlook for ATRP

K Matyjaszewski - European Polymer Journal, 2024 - Elsevier
Atom transfer radical polymerization (ATRP) is one of the most often used controlled radical
polymerization techniques. It employs very small amounts (ppm) of Cu complexes in the …

Effects of tailored dispersity on the self-assembly of dimethylsiloxane–methyl methacrylate block co-oligomers

B Oschmann, J Lawrence, MW Schulze… - ACS Macro …, 2017 - ACS Publications
The effect of dispersity on block polymer self-assembly was studied in the monodisperse
limit using a combination of synthetic chemistry, matrix-assisted laser desorption ionization …