[HTML][HTML] Critical review of fuel oxidation database under dry storage conditions

A Milena-Pérez, N Rodríguez-Villagra, F Feria… - Progress in Nuclear …, 2023 - Elsevier
Oxidation of spent nuclear fuel (SNF) with undetected cladding defects during dry storage
might challenge its integrity if high oxygen-content uranium oxides (U 3 O 8), characterized …

[HTML][HTML] Thermal air oxidation of UO2: Joint effect of precursor's nature and particle size distribution

A Milena-Pérez, N Rodríguez-Villagra… - Progress in Nuclear …, 2023 - Elsevier
The rate and extent of the air oxidation of UO 2 are of paramount importance due to its
relevance in the management of spent nuclear fuel at dry storage facilities. In particular, the …

Evolution of the uranium chemical state in mixed-valence oxides

G Leinders, R Bes, J Pakarinen, K Kvashnina… - Inorganic …, 2017 - ACS Publications
A fundamental question concerning the chemical state of uranium in the binary oxides UO2,
U4O9, U3O7, U3O8, and UO3 is addressed. By utilizing high energy resolution fluorescence …

Local Structure in U(IV) and U(V) Environments: The Case of U3O7

G Leinders, R Bes, KO Kvashnina… - Inorganic …, 2020 - ACS Publications
A comprehensive analysis of X-ray absorption data obtained at the UL 3-edge for a
systematic series of single-valence (UO2, KUO3, UO3) and mixed-valence uranium …

Laboratory-scale X-ray absorption spectroscopy approach for actinide research: Experiment at the uranium L3-edge

R Bès, T Ahopelto, AP Honkanen, S Huotari… - Journal of Nuclear …, 2018 - Elsevier
We report that by using crystal optics and laboratory-based X-ray source, one may perform
easily X-ray Absorption Spectroscopy (XAS) state-of-the-art measurements at the UL 3 …

Structural properties of ultra-small thorium and uranium dioxide nanoparticles embedded in a covalent organic framework

LM Moreau, A Herve, MD Straub, DR Russo… - Chemical …, 2020 - pubs.rsc.org
We report the structural properties of ultra-small ThO2 and UO2 nanoparticles (NPs), which
were synthesized without strong binding surface ligands by employing a covalent organic …

New insights into the structural transition from UO 2+ x to U 3 O 7 by quantitative Raman spectroscopy

JM Elorrieta, A Milena-Pérez, JF Vigier… - Physical Chemistry …, 2022 - pubs.rsc.org
The study of uranium oxides at different conditions is of paramount importance in the nuclear
field, especially regarding characterization of the spent nuclear fuel behavior in dry storage …

Hydrothermal conversion of uranium (IV) oxalate into oxides: A comprehensive study

J Manaud, J Maynadié, A Mesbah… - Inorganic …, 2020 - ACS Publications
Within the development of future nuclear reactors, wet chemistry routes have been
investigated for the fabrication of advanced oxide fuels. In this frame, a multiparametric study …

Polyepitaxial grain matching to study the oxidation of uranium dioxide

J Wasik, J Sutcliffe, R Podor, J Lewis… - npj Materials …, 2024 - nature.com
Although the principal physical behaviour of a material is inherently connected to its
fundamental crystal structure, the behaviours observed in the real-world are often driven by …

Insight into the structure–property relationship of UO 2 nanoparticles

E Gerber, AY Romanchuk, S Weiss… - Inorganic Chemistry …, 2021 - pubs.rsc.org
Highly crystalline UO2 nanoparticles (NPs) with sizes of 2–3 nm were produced by fast
chemical deposition of uranium (IV) under reducing conditions at pH 8–11. The particles …