C–H activation: toward sustainability and applications

T Dalton, T Faber, F Glorius - ACS Central Science, 2021 - ACS Publications
Since the definition of the “12 Principles of Green Chemistry” more than 20 years ago,
chemists have become increasingly mindful of the need to conserve natural resources and …

Recent advances in enantioselective Pd-catalyzed allylic substitution: from design to applications

O Pamies, J Margalef, S Canellas, J James… - Chemical …, 2021 - ACS Publications
This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

New strategies for the transition-metal catalyzed synthesis of aliphatic amines

A Trowbridge, SM Walton, MJ Gaunt - Chemical reviews, 2020 - ACS Publications
Transition-metal catalyzed reactions that are able to construct complex aliphatic amines from
simple, readily available feedstocks have become a cornerstone of modern synthetic …

Transition metal-catalyzed C–H amination: scope, mechanism, and applications

Y Park, Y Kim, S Chang - Chemical reviews, 2017 - ACS Publications
Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient
synthetic approach to construct N-functionalized molecules. Over the last few decades …

The Cross‐Dehydrogenative Coupling of C H Bonds: A Versatile Strategy for C C Bond Formations

SA Girard, T Knauber, CJ Li - … Chemie International Edition, 2014 - Wiley Online Library
Over the last decade, substantial research has led to the introduction of an impressive
number of efficient procedures which allow the selective construction of C C bonds by …

Metal-free photosensitized oxyimination of unactivated alkenes with bifunctional oxime carbonates

T Patra, M Das, CG Daniliuc, F Glorius - Nature Catalysis, 2021 - nature.com
Abstract The 1, 2-aminoalcohol motif is one of the most prevalent structural components
found in high-value organic molecules, including pharmaceuticals and natural products …

C H Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

J Yamaguchi, AD Yamaguchi… - Angewandte Chemie …, 2012 - Wiley Online Library
The direct functionalization of C H bonds in organic compounds has recently emerged as a
powerful and ideal method for the formation of carbon–carbon and carbon–heteroatom …

Palladium-catalyzed asymmetric allylic C–H functionalization: mechanism, stereo-and regioselectivities, and synthetic applications

PS Wang, LZ Gong - Accounts of Chemical Research, 2020 - ACS Publications
Conspectus Asymmetric functionalization of inert C–H bonds is undoubtedly a synthetically
significant yet challenging bond-forming process, allowing for the preparation of densely …

From C (sp 2)–H to C (sp 3)–H: systematic studies on transition metal-catalyzed oxidative C–C formation

BJ Li, ZJ Shi - Chemical Society Reviews, 2012 - pubs.rsc.org
In this tutorial review, we will summarize our recent efforts in transition metal-catalyzed
oxidative coupling via C–H functionalization of aromatic, benzylic and allylic C–H bonds …

Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

R Giri, BF Shi, KM Engle, N Maugel… - Chemical Society Reviews, 2009 - pubs.rsc.org
This critical review discusses historical and contemporary research in the field of transition
metal-catalyzed carbon–hydrogen (C–H) bond activation through the lens of …